{"id":"W2170317898","doi":"10.1002/chem.200600395","title":"Unexpected Reaction of the Unsaturated Cluster Host and Catalyst [Pd<sub>3</sub>(μ<sup>3</sup>‐CO)(dppm)<sub>3</sub>]<sup>2+</sup> with the Hydroxide Ion: Spectroscopic and Kinetic Evidence of an Inner‐Sphere Mechanism","year":2006,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Hydroxide; Adduct; Tetrahydrofuran; Medicinal chemistry; Catalysis; Inorganic chemistry; Radical; Electron paramagnetic resonance; Solvent; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007890729,0.0005764757,0.0005746944,0.0001122289,0.0004869293,0.0002101493,0.0007346291,0.0001861913,0.0000809904],"category_scores_gemma":[0.0002300993,0.0003916857,0.0002053703,0.001056775,0.0005052285,0.0003923282,0.0001990551,0.001117006,0.000009125103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001811349,"about_ca_system_score_gemma":0.0001850392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002893904,"about_ca_topic_score_gemma":0.000009476206,"domain_scores_codex":[0.9965221,0.0003508338,0.001030247,0.0006919611,0.0008820963,0.0005227193],"domain_scores_gemma":[0.9970143,0.0001786928,0.001160219,0.0009447151,0.0004008641,0.0003011497],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000194918,0.0001345459,0.0002855732,0.000245996,0.0001866207,0.00008809243,0.0005848641,0.0006076649,0.996282,0.000007417983,0.0003214371,0.001060918],"study_design_scores_gemma":[0.001685234,0.0001011374,0.001165266,0.000534717,0.0004078424,0.001746552,0.001782274,0.006829313,0.9850904,0.00003166282,0.0001923942,0.0004331647],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961779,0.00093903,0.000165988,0.0004260963,0.00002688266,0.0001793129,0.00003255104,0.00006826856,0.00198399],"genre_scores_gemma":[0.9986177,0.0002903339,0.00007462735,0.00008028841,0.0004387424,0.000008516447,0.00008227799,0.0001016308,0.0003058914],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01119151,"threshold_uncertainty_score":0.9998535,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006936053252793464,"score_gpt":0.1999171632188056,"score_spread":0.1929811099660121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}