{"id":"W2170744084","doi":"10.1039/c5dt02912k","title":"Brønsted acid-promoted C–F bond activation in [P,S]-ligated neutral and anionic perfluoronickelacyclopentanes","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Brønsted–Lowry acid–base theory; Chemistry; Medicinal chemistry; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001544404,0.0002750923,0.0001931086,0.0001777012,0.000164044,0.0002008607,0.0003123036,0.0002804823,0.001472616],"category_scores_gemma":[0.0001633852,0.0001394172,0.0001621455,0.0001095334,0.0002172592,0.0003041797,0.0002671102,0.000252325,0.0003486111],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002869526,"about_ca_system_score_gemma":0.0001702757,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005198501,"about_ca_topic_score_gemma":0.001348982,"domain_scores_codex":[0.9998785,0.00002099558,0.000008398891,0.00002298617,0.00002500828,0.00004407319],"domain_scores_gemma":[0.999958,0.000007062866,0.000008575525,0.00000581333,0.000006763617,0.00001375499],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001961266,0.00002809176,0.0001348088,0.0001055957,0.000007611313,0.000145645,0.00008465019,0.0002359042,0.99546,0.0006313829,0.00008517558,0.002884964],"study_design_scores_gemma":[0.00001641102,0.0002920798,0.0006201964,0.000005392552,0.000005572741,0.0001066882,0.00002372974,0.0005214234,0.9961674,0.000060693,0.002172857,0.000007598613],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927209,0.000686708,0.00147702,0.00004542004,0.00001434041,0.00002067318,0.00008947391,0.00006641247,0.004879158],"genre_scores_gemma":[0.9955279,0.0003176614,0.001292614,0.00001888563,0.000004938982,0.00001219836,0.0001069198,0.00001117286,0.002707543],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001472616,"threshold_uncertainty_score":0.004926383,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0847599942321749,"score_gpt":0.3823083320469537,"score_spread":0.2975483378147789,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}