{"id":"W2170891052","doi":"10.1139/v02-040","title":"Size dependence of the solubility of nonpolar compounds in different solvents","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Solvation; Solvent; Solubility; Enthalpy; Thermodynamics; Hexane; Solvent effects; Cyclohexane; Gibbs free energy; Hildebrand solubility parameter; Benzene; Computational chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002454577,0.0004028706,0.0002225441,0.0006540006,0.0001823423,0.0002164037,0.0003882977,0.0001819026,0.003031928],"category_scores_gemma":[0.0008975998,0.0001765673,0.0002238942,0.0004229278,0.0004714433,0.0005525134,0.0003034917,0.0005792194,0.0004060076],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002415228,"about_ca_system_score_gemma":0.000204151,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001298237,"about_ca_topic_score_gemma":0.00192884,"domain_scores_codex":[0.9998057,0.00002272807,0.0000105245,0.0000454867,0.00008969005,0.00002578016],"domain_scores_gemma":[0.9993615,0.0003729441,0.0001055745,0.00003135394,0.0000939483,0.00003468736],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002896379,0.00004071297,0.002111182,0.0001800692,0.0000319561,0.0001415785,0.0002007559,0.002957258,0.9881529,0.0005856138,0.0001938325,0.005114446],"study_design_scores_gemma":[0.000008776465,0.0002557919,0.01215612,0.000008126894,0.00001472069,0.0001081307,0.00007641406,0.00460707,0.9815056,0.0003175347,0.0009220838,0.00001962578],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987616,0.001466098,0.003997972,0.0001226272,0.00003997466,0.00003100539,0.0008434195,0.0002183335,0.005664479],"genre_scores_gemma":[0.99524,0.0006871503,0.001329778,0.00002520263,0.00001218667,0.00006185769,0.0007938119,0.00004839705,0.001801596],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003031928,"threshold_uncertainty_score":0.01014286,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009362654693539868,"score_gpt":0.1795347808173879,"score_spread":0.170172126123848,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}