{"id":"W2171515789","doi":"10.1002/anie.200901636","title":"Reversible Metal‐Free Carbon Dioxide Binding by Frustrated Lewis Pairs","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":758,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Nederlandse Organisatie voor Wetenschappelijk Onderzoek","keywords":"Borane; Frustrated Lewis pair; Phosphine; Chemistry; Lewis acids and bases; Metal; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001127131,0.0002535784,0.0003300486,0.0001217002,0.0003449194,0.0004790261,0.0005652202,0.000348099,0.002208634],"category_scores_gemma":[0.0002087857,0.000232462,0.00009690846,0.0001529311,0.0004506681,0.0004209986,0.0008728843,0.0003515244,0.0003837461],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003459809,"about_ca_system_score_gemma":0.0001522162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005943938,"about_ca_topic_score_gemma":0.0009904858,"domain_scores_codex":[0.9998692,0.00001690884,0.000004933948,0.00001749196,0.00003706278,0.00005439347],"domain_scores_gemma":[0.9999257,0.00001922794,0.00001139396,0.00001912934,0.000006838889,0.00001762393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004853575,0.00006599555,0.0003860978,0.0002162719,0.00005301603,0.0005887126,0.0002608911,0.003634427,0.9698418,0.01541339,0.001631076,0.00742288],"study_design_scores_gemma":[0.0001679833,0.0003027944,0.000610526,0.000008554178,0.00001724181,0.0002717775,0.00008759803,0.01853775,0.9710675,0.001826366,0.007044987,0.00005692307],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923669,0.0002834364,0.002256117,0.00007463423,0.00002502001,0.00001402303,0.00005111594,0.0001415227,0.004787367],"genre_scores_gemma":[0.9986153,0.00006454963,0.0003953004,0.00002269842,0.000003680971,0.000008009949,0.00002752776,0.00001512962,0.0008478891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002208634,"threshold_uncertainty_score":0.007388592,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01156323110995318,"score_gpt":0.2331458500653257,"score_spread":0.2215826189553725,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}