{"id":"W2171685803","doi":"10.1139/v08-126","title":"Formation of a [2]rotaxane and [2]catenane based on PdBr<sub>2</sub>L<sub>2</sub> as a template","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Rotaxane; Chemistry; Catenane; Palladium; Hydrogen bond; Supramolecular chemistry; Steric effects; Crystallography; Bromide; Stereochemistry; Crystal structure; Molecule; Catalysis; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001875954,0.0003656976,0.0004958568,0.0001129073,0.0002239971,0.00005121184,0.0003953323,0.0003248384,0.0002148675],"category_scores_gemma":[0.0003117561,0.0003827375,0.0002553533,0.0002163795,0.0002967776,0.0001941185,0.00002420419,0.0006104675,0.00001060663],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002333172,"about_ca_system_score_gemma":0.00138575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000118623,"about_ca_topic_score_gemma":0.00008263442,"domain_scores_codex":[0.9979522,0.00002284816,0.0007673064,0.0002894728,0.0004456343,0.0005225962],"domain_scores_gemma":[0.9975016,0.0001005717,0.0006873517,0.0004410489,0.0002929309,0.0009765296],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001374855,0.0000525119,0.0004291444,0.0004896862,0.0000626173,0.0009849634,0.0001937331,0.0001942925,0.9949244,0.000002231925,0.001210871,0.001318077],"study_design_scores_gemma":[0.001386641,0.00006139281,0.00009972697,0.0005174877,0.00006070219,0.004084758,0.0001941863,0.0003285934,0.9915622,0.0001258565,0.001208826,0.0003696189],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935563,0.0004236217,0.00008805663,0.0002750409,0.00005053383,0.00005743354,0.00006747272,0.00001864991,0.005462951],"genre_scores_gemma":[0.9992734,0.00008723317,0.00005779997,0.0001853045,0.0002197897,0.00000852524,0.00006074661,0.00004509215,0.00006214806],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00571712,"threshold_uncertainty_score":0.9998624,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01071351695754571,"score_gpt":0.1871043849250628,"score_spread":0.1763908679675171,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}