{"id":"W2172182439","doi":"10.1021/jp0367981","title":"Electrogenerated Chemiluminescence. 74. Photophysical, Electrochemical, and Electrogenerated Chemiluminescent Studies of Selected Nonplanar Pyrenophanes","year":2003,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chemiluminescence; Excimer; Photochemistry; Pyrene; Emission spectrum; Quantum yield; Fluorescence; Electrochemistry; HOMO/LUMO; Spectral line; Physical chemistry; Molecule; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003434485,0.0004641514,0.0009885237,0.00003187518,0.0001616777,0.00003348538,0.0005275974,0.0001328394,0.0001153867],"category_scores_gemma":[0.0007217487,0.0003052116,0.0002376162,0.0005004257,0.000474043,0.00009883411,0.00006361167,0.0005454458,0.000001712717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000113016,"about_ca_system_score_gemma":0.0002482074,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006022597,"about_ca_topic_score_gemma":5.088746e-7,"domain_scores_codex":[0.9977363,0.00007488022,0.0008178299,0.0002834064,0.0005570345,0.0005304921],"domain_scores_gemma":[0.9972748,0.0005309701,0.0007594935,0.0004168879,0.0008293928,0.000188432],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003479734,0.0004881126,0.0000369476,0.0004022089,0.0006729173,0.000006691872,0.0003927531,0.00001782882,0.9968538,0.00001785634,0.0006490286,0.0001139336],"study_design_scores_gemma":[0.0007967934,0.0001702848,0.000004784064,0.0002018847,0.0003769662,0.0003473476,0.0003782255,0.0006661182,0.9960971,0.0002920429,0.0003431151,0.0003253463],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944929,0.004531459,0.00001428431,0.0001363659,0.00001379989,0.00006859051,0.000004432477,0.00003140944,0.0007067891],"genre_scores_gemma":[0.9986015,0.0006444376,0.0001081097,0.0000388209,0.0003900086,0.0000100327,0.000008277372,0.00004517171,0.0001536168],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004108655,"threshold_uncertainty_score":0.99994,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01442898853807597,"score_gpt":0.2387280800527066,"score_spread":0.2242990915146306,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}