{"id":"W2172360206","doi":"10.1002/ange.201507883","title":"Palladium/Phosphaadamantan‐Katalysator ermöglicht die <i>trans</i>‐selektive Chlorcarbamoylierung von Alkinen","year":2015,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Ministerium für Innovation, Wissenschaft und Forschung des Landes Nordrhein-Westfalen; Canada Council for the Arts","keywords":"Chemistry; Palladium; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.001285119,0.001286656,0.001350677,0.0002033818,0.000315681,0.0003133229,0.001088933,0.001051078,0.004106796],"category_scores_gemma":[0.001440161,0.001414336,0.0006769673,0.0009519106,0.0005118198,0.000535198,0.0004498269,0.001100884,0.0009852784],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001311241,"about_ca_system_score_gemma":0.001106882,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004032552,"about_ca_topic_score_gemma":0.00008493965,"domain_scores_codex":[0.9934064,0.0001207298,0.001468266,0.001770615,0.001779386,0.001454675],"domain_scores_gemma":[0.9941155,0.0007198864,0.0007397239,0.001911223,0.001037102,0.001476506],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001496479,0.0009997052,0.007872794,0.001382481,0.003299814,0.0007174258,0.006788538,0.0001625707,0.7226675,0.0003484721,0.2519969,0.00226742],"study_design_scores_gemma":[0.002625615,0.00005609358,0.000129368,0.0002106988,0.0009749533,0.00003342857,0.0005268978,0.0000986443,0.5855178,0.0003677519,0.4085061,0.0009527403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.278797,0.2707756,0.008742303,0.01026222,0.02735157,0.00385966,0.007421781,0.003544867,0.389245],"genre_scores_gemma":[0.8096441,0.008838504,0.004715992,0.004309978,0.0209155,0.0005024181,0.01377637,0.001257373,0.1360398],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5308471,"threshold_uncertainty_score":0.9999885,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02825799223623053,"score_gpt":0.2727593665149355,"score_spread":0.244501374278705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}