{"id":"W2172477376","doi":"10.1002/chin.200517146","title":"Design of a Nonreductive Method for Chemoselective Cleavage of Hydrazines in the Presence of Unsaturations: Application to a Stereoconvergent Three‐Component Synthesis of (‐)‐Methyl Palustramate.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"","keywords":"Chemistry; Component (thermodynamics); Cleavage (geology); Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006764219,0.0009570982,0.0005812794,0.0003181221,0.0002419344,0.0004771092,0.00101106,0.0006159164,0.001850363],"category_scores_gemma":[0.0004323198,0.0004737168,0.0004605817,0.0002141618,0.0003757825,0.0006015612,0.000498219,0.001078908,0.001502875],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004341948,"about_ca_system_score_gemma":0.0007082968,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004671156,"about_ca_topic_score_gemma":0.001210306,"domain_scores_codex":[0.9996518,0.00005031623,0.00003400897,0.000123866,0.00009225071,0.0000478746],"domain_scores_gemma":[0.9997882,0.00003418779,0.00005680043,0.00004072208,0.00003612728,0.00004394021],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008508344,0.000098572,0.0000753194,0.0001268706,0.00001768929,0.00008396382,0.00003831465,0.0002576797,0.9882419,0.0004119861,0.0001386158,0.01042411],"study_design_scores_gemma":[0.00005405142,0.0004634679,0.0002422313,0.000004848389,0.00002157668,0.0001941496,0.00001251048,0.001028446,0.9931497,0.00007777424,0.004735962,0.00001530782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5831401,0.004063295,0.3962996,0.0007395291,0.0004215624,0.002533303,0.001295945,0.002574823,0.00893198],"genre_scores_gemma":[0.8028151,0.00299835,0.1833651,0.000216075,0.0000753137,0.000780091,0.001763656,0.0002595127,0.007726895],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001850363,"threshold_uncertainty_score":0.006190121,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02064189854395064,"score_gpt":0.2803614643941648,"score_spread":0.2597195658502141,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}