{"id":"W2172480352","doi":"10.1039/b305161g","title":"A novel palladium-catalyzed coupling of epoxides with allyl bromide mediated by indium(<scp>i</scp>) chloride: a cascade epoxide rearrangement–carbonyl allylation","year":2003,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Epoxide; Chemistry; Palladium; Catalysis; Aldehyde; Bromide; Cascade; Chloride; Allyl bromide; Indium; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001571985,0.0005609264,0.000371289,0.0002936347,0.0001500599,0.0003273361,0.0006877958,0.0004367934,0.001053528],"category_scores_gemma":[0.0001199196,0.000331809,0.0002972205,0.0001798199,0.000206233,0.0004160982,0.0003761169,0.0008335686,0.0008113586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003063713,"about_ca_system_score_gemma":0.0003278818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005196352,"about_ca_topic_score_gemma":0.0010152,"domain_scores_codex":[0.9998649,0.00001100025,0.00001075281,0.00004086168,0.00003857691,0.00003378499],"domain_scores_gemma":[0.9999366,0.00000758901,0.00001441231,0.000008969174,0.00001007173,0.00002237437],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003722536,0.00003577126,0.00005045817,0.00006395052,0.000009241026,0.0001488402,0.00001507074,0.0001024246,0.9952348,0.0002749323,0.00008109507,0.003946167],"study_design_scores_gemma":[0.00001258441,0.0001015826,0.0002061439,0.000001843287,0.00001206857,0.0002006928,0.000003306205,0.0003319826,0.9968423,0.00002509561,0.002257452,0.000005027026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8777184,0.006066042,0.09553633,0.0003327719,0.0002397159,0.0004033103,0.0005326428,0.001335931,0.01783474],"genre_scores_gemma":[0.9569721,0.002768505,0.03028448,0.00007150989,0.0000295235,0.00007696323,0.0003858679,0.0000568016,0.00935411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001053528,"threshold_uncertainty_score":0.003524423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02272429865862586,"score_gpt":0.2418943677522005,"score_spread":0.2191700690935747,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}