{"id":"W2172651316","doi":"10.1021/jo0608873","title":"Biosynthesis of 13-Desmethyl Spirolide C by the Dinoflagellate<i>Alexandrium</i><i>o</i><i>stenfeldii</i>","year":2006,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Marine Toxins and Detection Methods","field":"Environmental Science","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institute for Marine Biosciences","funders":"","keywords":"Chemistry; Dinoflagellate; Imine; Desmethyl; Biosynthesis; Stereochemistry; Moiety; Glycine; Nuclear magnetic resonance spectroscopy; Biochemistry; Amino acid; Metabolite; Botany; Enzyme; Biology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00152481,0.0001673566,0.0002520519,0.000009570048,0.0001465673,0.00002177642,0.0006812051,0.000085361,0.008178005],"category_scores_gemma":[0.0001274562,0.00009036501,0.0001574588,0.000306674,0.0003037829,0.00008005501,0.0001926345,0.0003465059,0.00002635711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007537112,"about_ca_system_score_gemma":0.00002367304,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001804499,"about_ca_topic_score_gemma":0.00001808358,"domain_scores_codex":[0.9984984,0.0001411687,0.0005676512,0.0001231198,0.0004520596,0.0002175999],"domain_scores_gemma":[0.9984641,0.0003885262,0.000620592,0.0004264103,0.00002864349,0.00007172477],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004490699,0.00006010518,0.001665011,0.00001269226,0.00002046153,0.000002127711,0.00004056136,0.0001317613,0.9866323,5.085988e-7,0.009804614,0.00158497],"study_design_scores_gemma":[0.0002949916,0.00003404957,0.002678654,0.00001175847,0.00008931945,0.0003043846,0.00009647063,0.00002708381,0.9790165,0.0003258678,0.01701131,0.000109619],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747961,0.0004314302,0.0009663387,0.0008296986,0.00009406947,0.00006113652,0.000005049552,0.00001195647,0.02280425],"genre_scores_gemma":[0.9945053,0.0002002934,0.0006352423,0.0001551241,0.0001953014,6.131496e-7,5.219665e-7,0.00002171834,0.004285843],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01970927,"threshold_uncertainty_score":0.9927287,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004122835440344053,"score_gpt":0.1965725190758336,"score_spread":0.1924496836354896,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}