{"id":"W2173301498","doi":"10.1002/chin.200606021","title":"Syntheses, <sup>77</sup>Se, <sup>203</sup>Tl, and <sup>205</sup>Tl NMR and Theoretical Studies of the Tl<sub>2</sub>Se<sup>6‐</sup><sub>6</sub>, Tl<sub>3</sub>Se<sup>5‐</sup><sub>6</sub>, and Tl<sub>3</sub>Se<sup>5‐</sup><sub>7</sub> Anions and the X‐Ray Crystal Structures of [2,2,2‐crypt‐Na]<sub>4</sub>[Tl<sub>4</sub>Se<sub>8</sub>]×en and [2,2,2‐crypt‐Na]<sub>2</sub> [Tl<sub>2</sub>Se<sub>4</sub>]<sup>1</sup><sub>∞</sub>×en.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Crystal Structures and Properties","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Radiochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.01935326,0.02531479,0.02510467,0.009249827,0.01545008,0.01097872,0.01628425,0.01518268,0.0004447065],"category_scores_gemma":[0.0140794,0.02301634,0.009998963,0.01458941,0.03442391,0.01488902,0.01894209,0.01810103,0.001315451],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.006663957,"about_ca_system_score_gemma":0.00656902,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001031176,"about_ca_topic_score_gemma":0.002362015,"domain_scores_codex":[0.9047121,0.006867608,0.02453769,0.02239478,0.01800682,0.02348103],"domain_scores_gemma":[0.9303434,0.0172954,0.01383859,0.01826252,0.008662125,0.01159798],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01332386,0.004103434,0.001838022,0.008676504,0.007667634,0.001623916,0.02818535,0.01624171,0.8184919,0.005665313,0.02345581,0.07072653],"study_design_scores_gemma":[0.02876541,0.004598102,0.003611574,0.007715956,0.009829733,0.007000474,0.02092714,0.02306541,0.8553945,0.01304662,0.004381638,0.0216634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.919104,0.02649575,0.0006566216,0.003172547,0.003834741,0.02244888,0.01671269,0.00498273,0.002592074],"genre_scores_gemma":[0.9187804,0.05084444,0.0008175249,0.003422113,0.009534296,0.005624099,0.005015016,0.005848782,0.0001133643],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04906313,"threshold_uncertainty_score":0.9999157,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01257165155318572,"score_gpt":0.2282043493780746,"score_spread":0.2156326978248889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}