{"id":"W2173715216","doi":"10.1021/ic0601945","title":"Pressure-Induced Internal Redox Reaction of Cs<sub>2</sub>[PdI<sub>4</sub>]·I<sub>2</sub>, Cs<sub>2</sub>[PdBr<sub>4</sub>]·I<sub>2</sub>, and Cs<sub>2</sub>[PdCl<sub>4</sub>]·I<sub>2</sub>","year":2006,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Isostructural; Redox; X-ray crystallography; Crystallography; Diffraction; Raman spectroscopy; Density functional theory; Raman scattering; Powder diffraction; Crystal structure; Inorganic chemistry; Physical chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001284899,0.000344785,0.0002360408,0.0001285786,0.0001740725,0.0003552044,0.0005243761,0.0002192701,0.001709969],"category_scores_gemma":[0.0003440762,0.0001716074,0.0001819239,0.000249697,0.0004023604,0.0002879468,0.0003503284,0.0004566427,0.000197328],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004171461,"about_ca_system_score_gemma":0.0003272097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001760512,"about_ca_topic_score_gemma":0.001874931,"domain_scores_codex":[0.9999021,0.00001030969,0.000005289007,0.00002280805,0.0000356104,0.00002382543],"domain_scores_gemma":[0.9999254,0.0000166064,0.00001657574,0.00001158688,0.00001944073,0.00001039899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002293349,0.00002204574,0.0002026455,0.000113417,0.00001330867,0.00006474483,0.00008547686,0.0005529171,0.9944555,0.0009388044,0.0001925621,0.003129215],"study_design_scores_gemma":[0.000009148181,0.00005345125,0.0002940755,0.000001257663,0.000004562952,0.00003192502,0.00001667076,0.0009618234,0.9977252,0.00005532861,0.0008422196,0.000004362333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893547,0.0005448346,0.003071842,0.00008387715,0.00003336673,0.00003862908,0.0003351588,0.0001610221,0.006376438],"genre_scores_gemma":[0.9955798,0.0002780085,0.00172411,0.00001850676,0.000005660166,0.00001551268,0.00037087,0.00002973395,0.001977709],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001760512,"threshold_uncertainty_score":0.005720437,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007225063409534134,"score_gpt":0.2010943256350001,"score_spread":0.193869262225466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}