{"id":"W2175067318","doi":"10.1021/jo025822o","title":"Remote Electronic Effects in the Rhodium-Catalyzed Nucleophilic Ring Opening of Oxabenzonorbornadienes","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"AstraZeneca","keywords":"Regioselectivity; Nucleophile; Rhodium; Ring (chemistry); Chemistry; Catalysis; Medicinal chemistry; Diamine; Combinatorial chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00031277,0.0004067121,0.0002414921,0.0001133139,0.000171401,0.0002877731,0.0002996515,0.0002452843,0.001511529],"category_scores_gemma":[0.0002141539,0.0001577663,0.000208324,0.00007644353,0.0003246193,0.0004059209,0.0002976416,0.0004854783,0.0004027188],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001625102,"about_ca_system_score_gemma":0.0001450654,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002673867,"about_ca_topic_score_gemma":0.0006279292,"domain_scores_codex":[0.9998469,0.00002857286,0.00001196755,0.00003250866,0.00003611245,0.00004386784],"domain_scores_gemma":[0.9998965,0.0000325666,0.00003111384,0.00001583483,0.000008098276,0.00001587925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009602524,0.00004568571,0.00008510042,0.00009696027,0.00000679084,0.0002584636,0.00007538716,0.0003733922,0.9947143,0.0006254026,0.00002531179,0.003597137],"study_design_scores_gemma":[0.00001551082,0.0003401248,0.0003598224,0.000003801591,0.00001014253,0.0003106821,0.00001461001,0.0003548888,0.9970367,0.00005732006,0.001488434,0.000007979651],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9900288,0.002071072,0.003564545,0.00007873168,0.00002581048,0.00003206688,0.00004489428,0.0000569207,0.004097194],"genre_scores_gemma":[0.9936512,0.001403417,0.003080405,0.0000200934,0.00001094691,0.00001075609,0.00004831542,0.00001334379,0.001761616],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001511529,"threshold_uncertainty_score":0.00505662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01386282879186271,"score_gpt":0.2422974176216065,"score_spread":0.2284345888297438,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}