{"id":"W2175344488","doi":"10.1139/v01-116","title":"Cadmium complexes of thiones. Part II.<sup>1</sup> A synthetic, solution, and solid-state MAS <sup>111/113</sup>Cd NMR study of cadmium complexes of 1,3-thiazolidine-2-thione, and the structures of [tetrakis(1,3-thiazolidine-2-thione)cadmium] trifluoromethanesulfonate ([Cd(C<sub>3</sub>H<sub>5</sub>NS<sub>2</sub>)<sub>4</sub>](CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>) and [tetrakis(1,3-thiazolidine-2-thione)cadmium][tetrakis(nitrato-<i>O,O</i><i>'</i>)cadmate] ([Cd(C<sub>3</sub>H<sub>5</sub>NS<sub>2</sub>)<sub>4</sub>][Cd(O<sub>2</sub>NO)<sub>4</sub>])","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Thiazolidine; Crystallography; Orthorhombic crystal system; Molecule; Homoleptic; Cadmium; Crystal structure; Tetragonal crystal system; Monoclinic crystal system; Stoichiometry; Stereochemistry; Metal; Physical chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007975959,0.0002376076,0.0001307358,0.0001542423,0.0001778433,0.000184473,0.0002654823,0.0002776927,0.002055891],"category_scores_gemma":[0.0001840594,0.0001181178,0.0001010714,0.0001269203,0.0003160805,0.0002390314,0.0001999122,0.0002602914,0.0003364814],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002778857,"about_ca_system_score_gemma":0.0001199499,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006248287,"about_ca_topic_score_gemma":0.0008438729,"domain_scores_codex":[0.9999304,0.00001277092,0.000003742291,0.00001737542,0.00002303564,0.0000127801],"domain_scores_gemma":[0.9999368,0.0000205739,0.00001769997,0.000006345454,0.00001094668,0.00000763851],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001396364,0.00001233829,0.0001604269,0.00007259254,0.000005745318,0.00004248573,0.00003057857,0.0001190518,0.9977909,0.0002393069,0.00009430582,0.001292618],"study_design_scores_gemma":[0.00001262558,0.0001598291,0.001131221,0.000004388281,0.000007229611,0.0001292903,0.0000290792,0.0005525283,0.9943141,0.00008256952,0.003574025,0.000003192634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864306,0.003614303,0.004271808,0.0001212613,0.0000493501,0.00003555741,0.0002544265,0.00007587665,0.005146707],"genre_scores_gemma":[0.983634,0.00245668,0.004287221,0.0001427482,0.00002587518,0.00004054353,0.0008569434,0.00004614448,0.008509785],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002055891,"threshold_uncertainty_score":0.006877601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01781983518132566,"score_gpt":0.2286406114071956,"score_spread":0.2108207762258699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}