{"id":"W2175344488","doi":"10.1139/v01-116","title":"Cadmium complexes of thiones. Part II.<sup>1</sup> A synthetic, solution, and solid-state MAS <sup>111/113</sup>Cd NMR study of cadmium complexes of 1,3-thiazolidine-2-thione, and the structures of [tetrakis(1,3-thiazolidine-2-thione)cadmium] trifluoromethanesulfonate ([Cd(C<sub>3</sub>H<sub>5</sub>NS<sub>2</sub>)<sub>4</sub>](CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>) and [tetrakis(1,3-thiazolidine-2-thione)cadmium][tetrakis(nitrato-<i>O,O</i><i>'</i>)cadmate] ([Cd(C<sub>3</sub>H<sub>5</sub>NS<sub>2</sub>)<sub>4</sub>][Cd(O<sub>2</sub>NO)<sub>4</sub>])","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Thiazolidine; Crystallography; Orthorhombic crystal system; Molecule; Homoleptic; Cadmium; Crystal structure; Tetragonal crystal system; Monoclinic crystal system; Stoichiometry; Stereochemistry; Metal; Physical chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.0196787,0.01763645,0.02551664,0.01121586,0.009135119,0.003793859,0.01077865,0.01037247,0.0002264892],"category_scores_gemma":[0.01135573,0.01756274,0.009615922,0.01425028,0.01588396,0.007215298,0.005002299,0.01989803,0.0005453652],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.005774484,"about_ca_system_score_gemma":0.01498651,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001707722,"about_ca_topic_score_gemma":0.01241041,"domain_scores_codex":[0.9172143,0.009057156,0.02652344,0.01408131,0.0159786,0.0171452],"domain_scores_gemma":[0.9281784,0.008782343,0.02069176,0.01224109,0.01363751,0.01646886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01555358,0.006240088,0.00326277,0.01083311,0.011223,0.004144731,0.0100465,0.004051098,0.8949438,0.0006081211,0.01629307,0.02280016],"study_design_scores_gemma":[0.03181511,0.006269468,0.008055038,0.01015206,0.01203248,0.01481724,0.009015385,0.003456157,0.8840036,0.003657616,0.00215894,0.01456684],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9388953,0.02526376,0.0005598583,0.004361894,0.004847722,0.01400972,0.00940815,0.001882804,0.0007708012],"genre_scores_gemma":[0.9287964,0.05120157,0.000558716,0.003424556,0.006209039,0.002099087,0.003283747,0.004366475,0.00006044598],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02593781,"threshold_uncertainty_score":0.9999912,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01781983518132566,"score_gpt":0.2286406114071956,"score_spread":0.2108207762258699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}