{"id":"W2175576233","doi":"10.1021/jo070246n","title":"Isothiocyanates from Tosyl Chloride Mediated Decomposition of in Situ Generated Dithiocarbamic Acid Salts","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":184,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Triethylamine; Alkyl; Carbon disulfide; Dithiocarbamate; Amine gas treating; Chloride; Tosyl; Salt (chemistry); Aryl; Yield (engineering); Decomposition; Organic chemistry; In situ","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001134104,0.0002571205,0.000479144,0.00007836313,0.00004850682,0.0000174402,0.0007302865,0.0003097159,0.001440385],"category_scores_gemma":[0.0006026826,0.0002046046,0.0001332351,0.0003451796,0.000114768,0.0001138182,0.00007992078,0.0007114702,0.000006656566],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003509452,"about_ca_system_score_gemma":0.0001897949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005532618,"about_ca_topic_score_gemma":0.00006309953,"domain_scores_codex":[0.997877,0.00004271164,0.00110515,0.0001758876,0.0004894134,0.0003098341],"domain_scores_gemma":[0.997368,0.000852161,0.0009653086,0.0004602236,0.0002327197,0.0001215923],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004830714,0.0001491737,0.001513541,0.00005859579,0.0001089425,0.00005815028,0.0003030261,0.000005425798,0.9967589,4.746858e-7,0.0001383826,0.0004222826],"study_design_scores_gemma":[0.0008189835,0.00002197864,0.0010794,0.0002996011,0.0001037129,0.0001282383,0.0004811972,0.0000286741,0.996607,0.0001923753,0.0000442287,0.0001946159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971141,0.0008965683,0.0003684507,0.0001926967,0.00006287692,0.00004151566,0.00002505889,0.00005765789,0.001241066],"genre_scores_gemma":[0.9986489,0.0002891648,0.0005345737,0.00005965208,0.0003438402,9.833342e-7,0.00004046835,0.0000501721,0.00003229202],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001534745,"threshold_uncertainty_score":0.9994724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007697824716579122,"score_gpt":0.24157810161316,"score_spread":0.2338802768965809,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}