{"id":"W2178382407","doi":"10.1039/c5dt04154f","title":"Synthesis and electronic properties of polycyclic aromatic hydrocarbons doped with phosphorus and sulfur","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Région Bretagne; Institute of Circulatory and Respiratory Health; Centre National de la Recherche Scientifique; Université de Rennes 1; Agence Nationale de la Recherche","keywords":"Phosphole; Thiophene; Sulfur; Doping; Density functional theory; Chemistry; Ring (chemistry); Aromaticity; Computational chemistry; Phosphorus; Electrochemistry; Heteroatom; Organic chemistry; Molecule; Physical chemistry; Materials science; Optoelectronics; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007855032,0.000174082,0.0002701549,0.00007067167,0.00009768245,0.00004340905,0.00009527614,0.00006922004,0.000099094],"category_scores_gemma":[0.00002488239,0.0001421346,0.00003464229,0.0001607342,0.000141469,0.0001433379,0.000006250455,0.0001178109,0.000002840454],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000442356,"about_ca_system_score_gemma":0.0001208569,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001291307,"about_ca_topic_score_gemma":0.0000397921,"domain_scores_codex":[0.9991111,0.00001815494,0.0002464751,0.0002318326,0.0001760733,0.0002163217],"domain_scores_gemma":[0.999464,0.0000624629,0.00009962737,0.0002276934,0.00001160216,0.0001346526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001371494,0.0002512438,0.001204902,0.00008700847,0.0002569612,0.000001732203,0.001242779,0.000002167318,0.9888534,0.0000511437,0.000005082495,0.007906435],"study_design_scores_gemma":[0.0005626338,0.00007091628,0.001248003,0.0001235634,0.0002397833,0.00009500411,0.001189214,0.0003432209,0.9942443,0.00009225523,0.00153216,0.0002589481],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964988,0.0008865472,0.0008748848,0.000334245,0.00001941965,0.00006936724,0.00001175695,0.0000684738,0.001236532],"genre_scores_gemma":[0.9988918,0.0003399839,0.00009415745,0.00002032999,0.00001794256,0.00004165993,0.000004548459,0.00003225031,0.0005573414],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007647487,"threshold_uncertainty_score":0.5796078,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01635412625476053,"score_gpt":0.1984678094238304,"score_spread":0.1821136831690699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}