{"id":"W2178717965","doi":"10.1562/2005-02-17-ra-444","title":"Photogeneration and Chemistry of Biphenyl Quinone Methides from Hydroxybiphenyl Methanols†","year":2005,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Moiety; Flash photolysis; Ring (chemistry); Biphenyl; Aqueous solution; Photochemistry; Substituent; Quinone; Intramolecular force; Medicinal chemistry; Alkylation; Benzene; Stereochemistry; Organic chemistry; Reaction rate constant; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002181728,0.0003912125,0.0006122769,0.00003104033,0.0001083758,0.00002689809,0.0002718211,0.0004912613,0.003207248],"category_scores_gemma":[0.0003415389,0.0003892898,0.0001009479,0.00008758136,0.0005611915,0.0001486233,0.0001667741,0.0003029813,0.000004586805],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003806674,"about_ca_system_score_gemma":0.0000548049,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002481444,"about_ca_topic_score_gemma":0.00001415351,"domain_scores_codex":[0.9981802,0.00004477124,0.0005706037,0.000708877,0.0001468939,0.000348731],"domain_scores_gemma":[0.9983113,0.0005992455,0.0003372948,0.0004948038,0.00008981337,0.0001675317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001538244,0.00009505493,0.001810749,0.000199459,0.0001801154,0.000003065243,0.0004544534,0.00000360856,0.9932091,0.00001245428,0.00005920642,0.003818881],"study_design_scores_gemma":[0.0008134006,0.00001689231,0.000139287,0.0000888333,0.00007218296,0.00005155867,0.0003828231,0.0003635568,0.9930174,0.0005540163,0.00411916,0.0003808377],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9884632,0.003514887,0.00004894676,0.0001187345,0.00002627668,0.0001230115,0.0002911059,0.00007510727,0.007338692],"genre_scores_gemma":[0.9951898,0.0005383653,0.003126339,0.000125552,0.0003282168,0.0001275682,0.0002079477,0.00003396312,0.000322273],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007016419,"threshold_uncertainty_score":0.9998559,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01146159766213743,"score_gpt":0.2299439191794206,"score_spread":0.2184823215172831,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}