{"id":"W2179523739","doi":"10.1002/9780470682531.pat0085","title":"Photochemistry of Amines and Amino Compounds","year":2009,"lang":"en","type":"other","venue":"","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Iminium; Chemistry; Primary (astronomy); Photochemistry; Imine; Ammonia; Mechanistic organic photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008613599,0.0003722317,0.0001097559,0.0004481968,0.0002786671,0.0003007686,0.0002891201,0.0001718745,0.01611182],"category_scores_gemma":[0.00007590136,0.00007479158,0.0001307792,0.0003303152,0.0002197513,0.0003139617,0.0002926702,0.0002726865,0.001600602],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000817643,"about_ca_system_score_gemma":0.0001821047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001534917,"about_ca_topic_score_gemma":0.001938627,"domain_scores_codex":[0.9999155,0.000004162858,0.000001819005,0.00001875373,0.00004521251,0.00001468817],"domain_scores_gemma":[0.9999543,0.000006877531,0.00000611597,0.000009887384,0.0000158664,0.000006955562],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001615959,0.00006453269,0.001108409,0.0003720186,0.00001526755,0.0002302884,0.0001094591,0.001035193,0.8068212,0.02775795,0.00673175,0.1555924],"study_design_scores_gemma":[0.00000556344,0.00008233567,0.004295006,0.00001497872,0.000006839045,0.0002977201,0.00003584138,0.0009712237,0.8617719,0.001757061,0.1307536,0.000007964147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2112876,0.01102012,0.01131149,0.0003460675,0.000395401,0.00008453279,0.0007941124,0.000392126,0.7643686],"genre_scores_gemma":[0.6463753,0.007572853,0.003696944,0.0001511771,0.0001210655,0.00002941813,0.0005578985,0.00007231047,0.3414231],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01611182,"threshold_uncertainty_score":0.05389941,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007447686942185079,"score_gpt":0.226997333161422,"score_spread":0.2195496462192369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}