{"id":"W2180347098","doi":"10.1139/cjc-2013-0474","title":"Synthesis, structural characterization, and reactivity of Cp*Ru(<i>N</i>-phosphinoamidinate) complexes","year":2014,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Reactivity (psychology); Adduct; Carbon monoxide; Characterization (materials science); Crystallography; Ruthenium; Hydrogen; Stereochemistry; Borane; Medicinal chemistry; Catalysis; Organic chemistry; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001973318,0.0001323479,0.0003098425,0.00008208046,0.00008679894,0.00003689332,0.0002266191,0.0001136978,0.0009096843],"category_scores_gemma":[0.0005268425,0.0001291149,0.0000943015,0.0001712191,0.0001368635,0.000135448,0.00001320279,0.0001828616,0.000001054606],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008579821,"about_ca_system_score_gemma":0.0002861067,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004241982,"about_ca_topic_score_gemma":0.0001278547,"domain_scores_codex":[0.999101,0.00001373828,0.0003934535,0.0001253903,0.0001857789,0.0001806572],"domain_scores_gemma":[0.9985542,0.00009858375,0.0004961116,0.000186944,0.0002331839,0.000431001],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001035492,0.000008329093,0.01596872,0.0001729403,0.0000775494,0.00001046632,0.00016967,0.000004109348,0.966529,0.00004702362,0.0001086819,0.0168932],"study_design_scores_gemma":[0.000210668,0.000004652737,0.005708467,0.0000647972,0.00005108911,0.0001417513,0.0001237023,0.0001236759,0.9850907,0.00007798208,0.0082672,0.0001353256],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954386,0.0001980229,0.0001360345,0.0001810783,0.00003790461,0.00001157947,0.00007594151,0.000005698371,0.003915146],"genre_scores_gemma":[0.9993832,0.00002350376,0.00004190375,0.00003644525,0.0001352334,8.240137e-7,0.00003292874,0.00001414705,0.0003318709],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01856173,"threshold_uncertainty_score":0.9960406,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00585105913353541,"score_gpt":0.1916835813790195,"score_spread":0.1858325222454841,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}