{"id":"W2181935017","doi":"10.1007/b96861","title":"Excited States and Optical Spectroscopy of Nitronyl Nitroxides and their Lanthanide and Transition Metal Complexes","year":2012,"lang":"en","type":"book-chapter","venue":"Topics in current chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Excited state; Lanthanide; Absorption spectroscopy; Spectroscopy; Luminescence; Photochemistry; Absorption (acoustics); Ground state; Atomic physics; Optoelectronics; Ion; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001669152,0.0002046452,0.0002132872,0.000283325,0.0003687244,0.0003330456,0.0005996379,0.0004229076,0.004312316],"category_scores_gemma":[0.0001301523,0.0002257147,0.0001409704,0.0003497576,0.0003792298,0.0004620534,0.0003513664,0.0005460693,0.0004934958],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003568104,"about_ca_system_score_gemma":0.00009943252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003116573,"about_ca_topic_score_gemma":0.0005294093,"domain_scores_codex":[0.9999356,0.00001057595,0.000001818972,0.00001444375,0.00002584557,0.00001172761],"domain_scores_gemma":[0.9999367,0.00003700834,0.00000618011,0.000007296276,0.000007901942,0.000004884876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002755646,0.00009228839,0.0003589662,0.0003586438,0.00001971247,0.0002153927,0.0006408211,0.001305927,0.9208638,0.02935851,0.003036116,0.04347423],"study_design_scores_gemma":[0.00002522431,0.0003170039,0.003674551,0.00007181325,0.00002327023,0.0005937936,0.0002506902,0.007362188,0.9199942,0.01393531,0.05371711,0.00003497395],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.8114522,0.03109896,0.02929401,0.0009783074,0.0002249406,0.00004846187,0.0003796667,0.0003578952,0.1261657],"genre_scores_gemma":[0.9027371,0.01101066,0.008660442,0.0003435068,0.00008654118,0.00005762917,0.0005568609,0.0001613139,0.0763859],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.004312316,"threshold_uncertainty_score":0.01442611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02311289026817145,"score_gpt":0.2608452774682224,"score_spread":0.2377323872000509,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}