{"id":"W2184227174","doi":"10.1201/9780203911013.ch44","title":"Stoichiometry and Kinetics of Gas Phase Cyclohexene Epoxidation by a Silica-Supported tert-Butylperoxidititanium Complex","year":2002,"lang":"en","type":"book-chapter","venue":"Chemical industries","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Catalysis; Cyclohexene; Titanium; Chemistry; Selectivity; Aluminosilicate; Stoichiometry; Inorganic chemistry; Metal; Heterogeneous catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001015825,0.0001704602,0.0001569892,0.0001324277,0.00007546868,0.000398978,0.0002287563,0.0002087927,0.001845717],"category_scores_gemma":[0.0002028968,0.0001920904,0.0001105909,0.0001370961,0.0001216535,0.000292594,0.00005711129,0.000305741,0.0005326374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002778087,"about_ca_system_score_gemma":0.000107606,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001117898,"about_ca_topic_score_gemma":0.000681637,"domain_scores_codex":[0.9999119,0.000004937595,0.000004712016,0.00002718017,0.00003788973,0.00001326667],"domain_scores_gemma":[0.9998549,0.0000734923,0.00001765545,0.0000167496,0.00002571057,0.00001146922],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001489691,0.0000286179,0.0003271515,0.0000245253,0.000004467641,0.00002702776,0.00002240776,0.0003591197,0.9962203,0.0001549322,0.0001047921,0.002577713],"study_design_scores_gemma":[0.000004139934,0.00005570637,0.001767139,0.000001580108,0.0000034028,0.00003041369,0.000006978977,0.001989549,0.9956246,0.00003891355,0.0004739284,0.000003629039],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901793,0.001171886,0.003256125,0.0000646703,0.00003336417,0.00002046416,0.0008779882,0.00017883,0.004217393],"genre_scores_gemma":[0.9922327,0.0006951388,0.0008440115,0.00001874873,0.00000858435,0.00001615041,0.0007936176,0.00004273012,0.005348295],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001845717,"threshold_uncertainty_score":0.006174564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04805471253550418,"score_gpt":0.2666181339413581,"score_spread":0.218563421405854,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}