{"id":"W218671691","doi":"10.1023/a:1012767413357","title":"Amino Acid Derivatives as Protein Side-Chain Model Compounds: The Partial Molar Volumes and Heat Capacities of Some N-Acetyl-N′-methyl Amino Acid Amides in Aqueous Solution","year":2001,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":17,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Royal Society of Chemistry; Royal Society","keywords":"Chemistry; Aqueous solution; Dilution; Partial molar property; Thermodynamics; Chain (unit); Physical chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005239366,0.0003106187,0.0005078146,0.00008240921,0.0001338767,0.00004350618,0.000375822,0.0002574178,0.00001995613],"category_scores_gemma":[0.0005041318,0.0002474069,0.0001632717,0.0001307859,0.0005796281,0.000497393,0.0001405196,0.0007268489,0.000001441624],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003458932,"about_ca_system_score_gemma":0.000117142,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001396355,"about_ca_topic_score_gemma":0.00001155628,"domain_scores_codex":[0.9979349,0.00007846307,0.0008519015,0.0002348211,0.0004701843,0.0004297557],"domain_scores_gemma":[0.9989318,0.00008539984,0.0004143155,0.0002688774,0.0001753221,0.000124346],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003168619,0.00009601918,0.00008912807,0.0001951667,0.00009024142,0.0000174782,0.001280985,0.009084919,0.9877264,0.0000786161,0.00005904841,0.0009651229],"study_design_scores_gemma":[0.0008130201,0.00007818518,0.000103465,0.0003383391,0.00003254377,0.0002537945,0.001040283,0.1840096,0.8116469,0.001402498,0.00005179837,0.0002295568],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837481,0.007228298,0.007655129,0.0008128648,0.0000617367,0.0001674621,0.00001641727,0.00004131647,0.0002686316],"genre_scores_gemma":[0.9978765,0.0003292639,0.001173284,0.00005132379,0.0002330121,0.00001921073,0.000006745197,0.0000365939,0.0002740548],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1760795,"threshold_uncertainty_score":0.9999978,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01386046365988367,"score_gpt":0.2214486240220283,"score_spread":0.2075881603621446,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}