{"id":"W2187660794","doi":"10.1139/v01-013","title":"Synthesis and spectroscopic (<sup>1</sup>H NMR, ESR) characterization of new aryloxy-Mn(II) complexes: steric control over <i>O</i>- vs. phenyl-π-coordination of ArO<sup>-</sup> ligands (ArO<sup>-</sup> = C<sub>6</sub>H<sub>5</sub>O<sup>-</sup>, 4-methyl-C<sub>6</sub>H<sub>4</sub>O<sup>-</sup>, 3,5-dimethyl-C<sub>6</sub>H<sub>3</sub>O<sup>-</sup>, 2,6-di-<i>tert</i>-butyl-C<sub>6</sub>H<sub>3</sub>O<sup>-</sup>, 2,6-dimethyl-C<sub>6</sub>H<sub>3</sub>O<sup>-</sup>) to the \"Mn(II)Cp\" moiety, and their reactivity with carbon dioxide","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Steric effects; Ligand (biochemistry); Moiety; Reactivity (psychology); Nucleophile; Stereochemistry; Nuclear magnetic resonance spectroscopy; Electron paramagnetic resonance; Medicinal chemistry; Crystallography","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.01632903,0.02032374,0.02222193,0.01044461,0.008562206,0.005702097,0.01458531,0.01281004,0.0004606701],"category_scores_gemma":[0.01000666,0.02135231,0.009763706,0.01719402,0.008573498,0.01197741,0.005688454,0.02009287,0.0008386561],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01242161,"about_ca_system_score_gemma":0.01475281,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00187897,"about_ca_topic_score_gemma":0.002344799,"domain_scores_codex":[0.9182783,0.007126769,0.02235766,0.01754004,0.01551575,0.01918151],"domain_scores_gemma":[0.9293141,0.008923897,0.01825957,0.01582542,0.009546664,0.01813034],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.008618744,0.004867022,0.003548681,0.005632735,0.01017338,0.002861727,0.01363667,0.04662398,0.8564866,0.000162999,0.00833287,0.03905457],"study_design_scores_gemma":[0.02721683,0.003513487,0.002144513,0.008030133,0.008959263,0.007011012,0.009085732,0.05031923,0.8609369,0.001481882,0.004035427,0.01726552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9505407,0.006790699,0.005018109,0.004775881,0.001810435,0.01284873,0.01434352,0.002863778,0.001008127],"genre_scores_gemma":[0.952209,0.01376738,0.0009999495,0.004354029,0.009957642,0.003544357,0.008853723,0.006073864,0.0002400589],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02178905,"threshold_uncertainty_score":0.9999393,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008215708668069133,"score_gpt":0.1966796923305985,"score_spread":0.1884639836625293,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}