{"id":"W2187660794","doi":"10.1139/v01-013","title":"Synthesis and spectroscopic (<sup>1</sup>H NMR, ESR) characterization of new aryloxy-Mn(II) complexes: steric control over <i>O</i>- vs. phenyl-π-coordination of ArO<sup>-</sup> ligands (ArO<sup>-</sup> = C<sub>6</sub>H<sub>5</sub>O<sup>-</sup>, 4-methyl-C<sub>6</sub>H<sub>4</sub>O<sup>-</sup>, 3,5-dimethyl-C<sub>6</sub>H<sub>3</sub>O<sup>-</sup>, 2,6-di-<i>tert</i>-butyl-C<sub>6</sub>H<sub>3</sub>O<sup>-</sup>, 2,6-dimethyl-C<sub>6</sub>H<sub>3</sub>O<sup>-</sup>) to the \"Mn(II)Cp\" moiety, and their reactivity with carbon dioxide","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Steric effects; Ligand (biochemistry); Moiety; Reactivity (psychology); Nucleophile; Stereochemistry; Nuclear magnetic resonance spectroscopy; Electron paramagnetic resonance; Medicinal chemistry; Crystallography","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001046398,0.0002642759,0.000136162,0.00006786118,0.00009416341,0.0002210019,0.0003823041,0.000196434,0.001029312],"category_scores_gemma":[0.000219985,0.0001129617,0.00007961134,0.00009362797,0.0001639163,0.000164828,0.0001503048,0.0002967697,0.0003458798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002462127,"about_ca_system_score_gemma":0.0001178297,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005382544,"about_ca_topic_score_gemma":0.0008728922,"domain_scores_codex":[0.9999095,0.00001040703,0.000007234993,0.00002769904,0.00003094335,0.00001407233],"domain_scores_gemma":[0.9998916,0.00001555253,0.00003850413,0.00001669842,0.00002035642,0.00001722441],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001175654,0.00001653022,0.00007361567,0.00004671413,0.000003564011,0.00001887051,0.00002386448,0.00007651811,0.9981197,0.00008600808,0.0001022284,0.001314846],"study_design_scores_gemma":[0.00001002147,0.00005892836,0.0004344003,0.000001176192,0.000006203101,0.00004235841,0.000005075819,0.0002660474,0.9973392,0.00001065676,0.001823641,0.000002364648],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9719303,0.001174864,0.02079071,0.0001480382,0.00006378901,0.00009525143,0.0009244556,0.0003381501,0.004534374],"genre_scores_gemma":[0.9808426,0.0006948204,0.01189411,0.00009871579,0.00001490324,0.00007257095,0.0009207069,0.00009219154,0.005369407],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001029312,"threshold_uncertainty_score":0.00344342,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008215708668069133,"score_gpt":0.1966796923305985,"score_spread":0.1884639836625293,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}