{"id":"W2189958949","doi":"10.1039/c5gc02723c","title":"CO<sub>2</sub>-blown microcellular non-isocyanate polyurethane (NIPU) foams: from bio- and CO<sub>2</sub>-sourced monomers to potentially thermal insulating materials","year":2015,"lang":"en","type":"article","venue":"Green Chemistry","topic":"Polymer Foaming and Composites","field":"Materials Science","cited_by":206,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"","keywords":"Isocyanate; Polyurethane; Materials science; Monomer; Blowing agent; Supercritical carbon dioxide; Supercritical fluid; Composite material; Chemical engineering; Carbon dioxide; Thermal; Organic chemistry; Chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005495715,0.0006055946,0.0007080875,0.00008732732,0.0002922519,0.0003890118,0.0006866781,0.0003701109,0.0001002496],"category_scores_gemma":[0.00005877174,0.000624598,0.000118564,0.0002118588,0.000257145,0.0002341891,0.000295713,0.0002443394,0.0003156411],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001312178,"about_ca_system_score_gemma":0.0001708978,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008469857,"about_ca_topic_score_gemma":0.00001181271,"domain_scores_codex":[0.9966875,0.0001079812,0.0007151719,0.001019307,0.0005568996,0.000913117],"domain_scores_gemma":[0.9980131,0.00008661926,0.0003874055,0.0007041144,0.000120012,0.0006887616],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002532887,0.00005486244,0.0007818438,0.00008742499,0.00007057061,0.00006789171,0.0009178958,0.00002575595,0.994169,4.405817e-7,0.0002072575,0.003363779],"study_design_scores_gemma":[0.001284132,0.00006657738,0.0007751716,0.0001514896,0.00009376008,0.00004710689,0.0003105725,0.0001100077,0.996236,0.00005089093,0.0001252325,0.0007490389],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971311,0.0007076801,0.0002018671,0.0002490235,0.0003192428,0.0002608431,0.0005185172,0.0002280969,0.0003836418],"genre_scores_gemma":[0.9979727,0.00001711559,0.0006007043,0.0002982907,0.0005979,0.00003465137,0.0002813044,0.00009802599,0.00009931855],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00261474,"threshold_uncertainty_score":0.9996206,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01096411053904962,"score_gpt":0.2146036698152716,"score_spread":0.203639559276222,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}