{"id":"W2190748575","doi":"10.1139/cjc-2013-0270","title":"A mechanistic study of the [La<sub>2</sub>(OCH<sub>3</sub>)<sub>2</sub>]<sup>4+</sup>- and [(1,5,9-triazacyclodo-decane):Zn:(OCH<sub>3</sub>)]<sup>+</sup>-catalyzed methanolysis of carbonates: possible application for the recycling of bisphenol A polycarbonates","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Alkoxy group; Nucleophile; Alkyl; Medicinal chemistry; Reaction rate constant; Isopropyl; Methoxide; Substituent; Catalysis; Stereochemistry; Kinetics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001656333,0.0003713635,0.0003154667,0.00007282814,0.0001581179,0.0003155584,0.0004684082,0.0004181558,0.0007769109],"category_scores_gemma":[0.0001449809,0.000164021,0.0002342817,0.00009432858,0.0002694822,0.0003504189,0.0001744345,0.0003644092,0.0002348629],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004968984,"about_ca_system_score_gemma":0.0003321366,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001779879,"about_ca_topic_score_gemma":0.002561107,"domain_scores_codex":[0.9999081,0.00001360272,0.000004815173,0.00001920435,0.00003185029,0.00002254556],"domain_scores_gemma":[0.9999374,0.00001312707,0.00001735679,0.000006385609,0.00001627565,0.00000933896],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000144282,0.00002624115,0.0002958761,0.0001243399,0.00001085555,0.00005394161,0.00002335488,0.0003903365,0.997413,0.0001504891,0.00002500807,0.001342377],"study_design_scores_gemma":[0.000009651264,0.0001120012,0.00124314,0.000003749433,0.000009236734,0.00006588936,0.00002117375,0.001667567,0.9958547,0.00004902541,0.000957887,0.000005915621],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902867,0.002114855,0.005386061,0.0001620161,0.00002300364,0.0000739137,0.0002069808,0.00008035217,0.001666101],"genre_scores_gemma":[0.9957235,0.0008718179,0.001996252,0.00002606378,0.000004538095,0.00002530685,0.00008256592,0.000006705399,0.001263352],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001779879,"threshold_uncertainty_score":0.003605247,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008737790578588174,"score_gpt":0.2103551352828697,"score_spread":0.2016173447042815,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}