{"id":"W2196079181","doi":"10.1016/j.ica.2015.11.030","title":"Studies on the Ru(II) monocationic complexes [RuCl2(NO)(P–N)(PR3)]PF6, where P–N =o-diphenylphosphino-N,N-dimethylaniline, and R = Ph and p-X-C6H4 (X = OMe, Me, F)","year":2015,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"Conselho Nacional de Desenvolvimento Científico e Tecnológico; Financiadora de Estudos e Projetos; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior","keywords":"Chemistry; Dimethylaniline; Ion; Crystallography; Molecule; Stereochemistry; Ligand (biochemistry); Medicinal chemistry; Photochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003234408,0.0002401073,0.0004748054,0.0001407417,0.0004234805,0.0004297655,0.0005139763,0.0004616146,0.002744887],"category_scores_gemma":[0.0008239101,0.0001918624,0.0001373874,0.0002490342,0.0003071568,0.000290769,0.00018538,0.000394268,0.0004320722],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003519018,"about_ca_system_score_gemma":0.0001216276,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001542268,"about_ca_topic_score_gemma":0.001204392,"domain_scores_codex":[0.9996285,0.00007290373,0.00001565541,0.00006328793,0.0001049541,0.0001146093],"domain_scores_gemma":[0.9996675,0.0001243266,0.00004927304,0.00004950515,0.00008123324,0.0000281369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000910552,0.0001231435,0.0003650837,0.0004273453,0.00003517698,0.0001930314,0.0002518008,0.0002805721,0.9914221,0.0006534473,0.0006610087,0.004676757],"study_design_scores_gemma":[0.00007349026,0.0006931202,0.001516129,0.00001333597,0.0000372746,0.0004723037,0.00007653578,0.0007802656,0.9902617,0.00006517479,0.00599915,0.00001137228],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886812,0.002550932,0.001173278,0.0001528381,0.00004862629,0.00004484002,0.0001931176,0.00006882846,0.007086374],"genre_scores_gemma":[0.9953448,0.0006859126,0.0007334659,0.00005147323,0.00002228713,0.00001375863,0.0002091054,0.00002135555,0.002917661],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002744887,"threshold_uncertainty_score":0.009182572,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03591924130882595,"score_gpt":0.2571782835035018,"score_spread":0.2212590421946758,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}