{"id":"W2199912010","doi":"10.1038/srep16397","title":"Visible-Light Actinometry and Intermittent Illumination as Convenient Tools to Study Ru(bpy)3Cl2 Mediated Photoredox Transformations","year":2015,"lang":"en","type":"article","venue":"Scientific Reports","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":136,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Actinometer; Visible spectrum; Photochemistry; Chemistry; Photoredox catalysis; Photocatalysis; Optoelectronics; Materials science; Biochemistry; Catalysis; Plasma; Physics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001020489,0.0002288738,0.0002849653,0.0002918138,0.0002730597,0.0004829946,0.0002116216,0.0001225535,0.0006707717],"category_scores_gemma":[0.002241585,0.0002088177,0.0000918689,0.0008586039,0.0001781668,0.0005138268,0.000110362,0.0002626708,0.0001369223],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002974052,"about_ca_system_score_gemma":0.0001961218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006063294,"about_ca_topic_score_gemma":0.00001515756,"domain_scores_codex":[0.9968928,0.00003242555,0.0008246485,0.0008173489,0.001061062,0.0003717742],"domain_scores_gemma":[0.9976143,0.0001224702,0.0002667304,0.0008229062,0.0003529643,0.0008206684],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005730871,0.001300969,0.002572949,0.00005517389,0.0001051876,0.0003372493,0.007502096,0.00001179372,0.9614759,0.00003213724,0.01529832,0.0112509],"study_design_scores_gemma":[0.0009255783,0.0001398738,0.001226633,0.00008255611,0.0001057508,0.0004517359,0.006465387,0.0002770087,0.8469741,0.001400626,0.1414308,0.0005199073],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9782093,0.00004502732,0.0001334584,0.0004011618,0.001720484,0.0007457555,0.00001727161,0.000161619,0.01856591],"genre_scores_gemma":[0.9974004,0.000002170571,0.0001107702,0.00006001711,0.00005961541,0.0002390913,0.0001692176,0.00002361663,0.001935106],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1261325,"threshold_uncertainty_score":0.851534,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02628693390373632,"score_gpt":0.28539291345879,"score_spread":0.2591059795550537,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}