{"id":"W2204011411","doi":"10.1021/jacs.5b10124","title":"Description and Role of Bimetallic Prenucleation Species in the Formation of Small Nanoparticle Alloys","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Argonne National Laboratory; Division of Engineering Education and Centers; Natural Sciences and Engineering Research Council of Canada; University of Pittsburgh; Office of Science; Division of Chemistry; Research Corporation for Science Advancement; U.S. Department of Energy","keywords":"Chemistry; Bimetallic strip; Nanoparticle; X-ray photoelectron spectroscopy; Metal; Mass spectrometry; Spectroscopy; Aqueous solution; Nuclear magnetic resonance spectroscopy; Particle (ecology); Reagent; Chemical engineering; Nanotechnology; Physical chemistry; Stereochemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000201385,0.0001872776,0.000159386,0.0002203472,0.0002119809,0.000283853,0.0003468413,0.0002639272,0.0008465415],"category_scores_gemma":[0.0003658285,0.0001303616,0.0001057298,0.00009616255,0.0002679619,0.0003275087,0.0002448943,0.0002658184,0.0002397906],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003729599,"about_ca_system_score_gemma":0.0001686391,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003802516,"about_ca_topic_score_gemma":0.0009349808,"domain_scores_codex":[0.9998665,0.00001976529,0.00001417985,0.00005022808,0.00003937266,0.00001003488],"domain_scores_gemma":[0.9998554,0.00005335338,0.00002926668,0.00002767699,0.0000238027,0.00001042584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004999758,0.000008659755,0.0003772238,0.00006617794,0.000004727849,0.0000987395,0.00007103474,0.0003795694,0.9933351,0.001568973,0.00002751046,0.004012269],"study_design_scores_gemma":[0.000002360314,0.00004450979,0.0003079185,0.000001696901,0.000003550439,0.00009550293,0.000010039,0.001578642,0.9967284,0.0001229777,0.001101732,0.000002589491],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9684816,0.001533486,0.02575522,0.00008291306,0.00002627983,0.00006206503,0.000101228,0.0001840903,0.003773129],"genre_scores_gemma":[0.9839347,0.0003590416,0.0140522,0.00002324349,0.000005038712,0.00002750832,0.00006492423,0.00003445763,0.001498949],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008465415,"threshold_uncertainty_score":0.002831936,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02972490978845906,"score_gpt":0.2334212285016714,"score_spread":0.2036963187132123,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}