{"id":"W2212636086","doi":"10.1021/acs.jpcc.5b09826","title":"Controlled Intramolecular Charge Transfer Using a Sulfur-Containing Acceptor Group","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Acceptor; Intramolecular force; Photochemistry; Sulfur; Chromophore; Chemistry; Solvatochromism; Excited state; Molecule; Anthracene; Stereochemistry; Organic chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000501542,0.0003311458,0.0007556158,0.00001400701,0.0001413723,0.00004482322,0.0006067765,0.000113047,0.0002594577],"category_scores_gemma":[0.0001584657,0.0002214696,0.0004500802,0.0001348917,0.0001832675,0.0001517596,0.00004228503,0.0008111935,0.000004592294],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001569167,"about_ca_system_score_gemma":0.0001538349,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001165002,"about_ca_topic_score_gemma":3.466022e-7,"domain_scores_codex":[0.9982073,0.00004870399,0.0005408,0.0001771361,0.0005622078,0.0004638786],"domain_scores_gemma":[0.9988077,0.0002029335,0.0001713058,0.0002842832,0.0002489341,0.0002848903],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002570102,0.0002587102,0.0000187456,0.0001027174,0.0004390612,0.00002991127,0.00117103,0.00007290745,0.9950241,0.00002494737,0.00008749166,0.0002002806],"study_design_scores_gemma":[0.006203254,0.0001156846,0.000001479095,0.00007875469,0.0004514066,0.0001854093,0.0009909548,0.0008643122,0.9899344,0.0002635673,0.0006579175,0.0002528919],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916118,0.0006595475,0.0006900393,0.0001612082,0.00003729435,0.00007532593,0.00001065472,0.00002955938,0.006724614],"genre_scores_gemma":[0.9984484,0.00002507457,0.00002527089,0.00006065135,0.001268919,0.000008565169,0.000005285973,0.00003352328,0.0001242931],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006836661,"threshold_uncertainty_score":0.9031267,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02189508055306415,"score_gpt":0.2587019653185447,"score_spread":0.2368068847654806,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}