{"id":"W2217296958","doi":"10.1021/acs.jpclett.5b01837","title":"Real-Time and In Situ Monitoring of Mechanochemical Reactions: A New Playground for All Chemists","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":191,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Mechanochemistry; In situ; Metastability; Nanotechnology; Materials science; Mechanosynthesis; Reactivity (psychology); Raman spectroscopy; Synchrotron; Kinetics; Chemistry; Process engineering; Chemical engineering; Ball mill; Metallurgy; Engineering; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001688043,0.0001394481,0.0002548709,0.00002470903,0.00002281665,0.0000158509,0.0002086564,0.00006693598,0.00000778473],"category_scores_gemma":[0.0001492022,0.0001132949,0.000172824,0.00008329946,0.00007903393,0.00009652776,0.00003838417,0.0003257667,3.233784e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009056445,"about_ca_system_score_gemma":0.00005560813,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003731665,"about_ca_topic_score_gemma":5.507408e-7,"domain_scores_codex":[0.9991442,0.00001174167,0.0003379435,0.0001124202,0.0002223527,0.0001713368],"domain_scores_gemma":[0.9989933,0.0002818509,0.0003033592,0.0001783689,0.00008437054,0.000158753],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003339371,0.0001126977,0.00002937781,0.00009434437,0.0001024449,0.000006827562,0.0004771152,0.0001340026,0.9981093,0.000003701593,0.0005385395,0.0000576944],"study_design_scores_gemma":[0.0008844966,0.0000176818,0.00001457283,0.0001658606,0.0001066867,0.0001248402,0.0003328726,0.000088195,0.9973838,0.0003249782,0.0004502207,0.0001058154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984722,0.00006625281,0.0001176302,0.0006695776,0.00002365909,0.00003619899,0.000006645251,0.000008910765,0.0005988851],"genre_scores_gemma":[0.9987811,0.0000231142,0.0004785549,0.00001950523,0.0005812121,0.000003461629,0.000005970851,0.00001601989,0.00009105093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007255378,"threshold_uncertainty_score":0.4620031,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01874891696745469,"score_gpt":0.2761096369013654,"score_spread":0.2573607199339107,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}