{"id":"W2218953550","doi":"10.1063/1.4938028","title":"Realistic vs sudden turn-on of natural incoherent light: Coherences and dynamics in molecular excitation and internal conversion","year":2015,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Excitation; Turn (biochemistry); Physics; Inverse; Optics; Atomic physics; Nuclear magnetic resonance; Mathematics; Quantum mechanics; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001406342,0.00009247999,0.0002117758,0.00001614268,0.00001445335,0.0000107225,0.0001003986,0.00002123317,0.000002619163],"category_scores_gemma":[0.00002469573,0.00005815128,0.00003668869,0.0000658557,0.0001194638,0.00006640632,0.00005542043,0.0002415555,2.848871e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004533745,"about_ca_system_score_gemma":0.00001717869,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007995704,"about_ca_topic_score_gemma":0.000001254021,"domain_scores_codex":[0.9994065,0.00003578077,0.0002246055,0.00006249528,0.0001805603,0.0000901292],"domain_scores_gemma":[0.9994647,0.0001203743,0.0002243905,0.00005206759,0.00008510056,0.00005335551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002805405,0.0006533209,0.04648737,0.0001586509,0.0004359338,0.00001167669,0.005469855,0.0001471797,0.8802102,0.05496494,0.001657715,0.006997778],"study_design_scores_gemma":[0.00170857,0.0003882484,0.001065802,0.0002873627,0.0001060301,0.000007181166,0.002214403,0.00427672,0.8145329,0.1752196,0.000019195,0.0001740187],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984137,0.0001945628,0.0004205688,0.0003231877,0.00005935767,0.00004510631,0.000004812628,0.000001501471,0.0005371474],"genre_scores_gemma":[0.9997712,0.00001296417,0.00007365363,0.00002395303,0.0001053795,6.039174e-7,0.000003269736,0.000004605265,0.000004341885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1202547,"threshold_uncertainty_score":0.237134,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009605284887609833,"score_gpt":0.2535298145017136,"score_spread":0.2439245296141038,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}