{"id":"W2220819733","doi":"10.1016/j.ccr.2015.11.003","title":"The rich and varied chemistry of group 6 cyclopentadienyl nitrosyl complexes","year":2015,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Dow Chemical Company","keywords":"Chemistry; Cyclopentadienyl complex; Halide; Dimer; Valence (chemistry); Stereochemistry; Ligand (biochemistry); Lewis acids and bases; Group 2 organometallic chemistry; Group (periodic table); Alkyl; Medicinal chemistry; Main group element; Crystallography; Molecule; Inorganic chemistry; Transition metal; Organic chemistry; Catalysis; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002412965,0.0003812652,0.0002222054,0.0001572589,0.0002143759,0.0007311051,0.0005469194,0.0002925829,0.002305855],"category_scores_gemma":[0.0002007638,0.0002112493,0.0001022365,0.0001770143,0.0005550613,0.0007658062,0.000572623,0.0007344489,0.0005079466],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007312476,"about_ca_system_score_gemma":0.0002330047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005399382,"about_ca_topic_score_gemma":0.0008531709,"domain_scores_codex":[0.9998815,0.00002682893,0.000007431716,0.00003005328,0.00002801418,0.00002623276],"domain_scores_gemma":[0.9999464,0.00001852444,0.00001036006,0.000009229826,0.000006036851,0.000009396415],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003445311,0.00005129766,0.0001577509,0.0008440492,0.00002791001,0.0003575099,0.0008857699,0.00248958,0.8774059,0.07527888,0.003073957,0.03908285],"study_design_scores_gemma":[0.00005303607,0.0004712789,0.0009027946,0.00006522927,0.00003329104,0.0005698893,0.0002018298,0.00199962,0.8697879,0.00701511,0.1188526,0.00004732157],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"review","genre_scores_codex":[0.8241111,0.04332573,0.02297424,0.002653018,0.00061431,0.00007529766,0.0003187351,0.0006222852,0.1053053],"genre_scores_gemma":[0.9620037,0.01653677,0.003012413,0.0003450576,0.00007718335,0.00003777095,0.0001615521,0.00009475533,0.01773072],"genre_candidate":"review","genre_consensus":null,"teacher_disagreement_score":0.002305855,"threshold_uncertainty_score":0.007713914,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03476645573711917,"score_gpt":0.2602777398721271,"score_spread":0.2255112841350079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}