{"id":"W2221368739","doi":"10.1021/jacs.5b12003","title":"Perfluoroalkyl Cobalt(III) Fluoride and Bis(perfluoroalkyl) Complexes: Catalytic Fluorination and Selective Difluorocarbene Formation","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Difluorocarbene; Chemistry; Cobalt; Fluoride; Catalysis; Fluorine; Medicinal chemistry; Organic chemistry; Polymer chemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008898284,0.0002968093,0.0005503281,0.00003439385,0.0002162302,0.0000457604,0.0004240358,0.0001943039,0.00002011483],"category_scores_gemma":[0.0004434658,0.0002273616,0.0002321582,0.0004254268,0.0009437636,0.000310241,0.000315606,0.00124534,0.000003276769],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005787238,"about_ca_system_score_gemma":0.0002373967,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006082484,"about_ca_topic_score_gemma":0.000002123966,"domain_scores_codex":[0.9980837,0.0001715895,0.0006454043,0.0002636241,0.0004396181,0.0003960409],"domain_scores_gemma":[0.9976257,0.0004218312,0.00088573,0.0002138509,0.0004205912,0.0004322806],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003264025,0.0001615522,0.007162491,0.00005853713,0.0003323612,0.000005369931,0.002613985,0.0000381762,0.9467378,0.00004240072,0.02654473,0.01597618],"study_design_scores_gemma":[0.002929238,0.0002380722,0.002723471,0.00003622981,0.000489947,0.001091826,0.002111886,0.003178363,0.9717842,0.0004317069,0.01463953,0.0003455382],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931661,0.002742627,0.000106792,0.003101093,0.0003361809,0.0001923875,0.00001908606,0.00003653048,0.000299208],"genre_scores_gemma":[0.996271,0.0005954069,0.001117325,0.001286678,0.0005744948,0.000007253933,0.000007337312,0.00003056385,0.000110006],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02504638,"threshold_uncertainty_score":0.9271536,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05111941910406815,"score_gpt":0.3614341513914057,"score_spread":0.3103147322873376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}