{"id":"W2233926886","doi":"10.1021/acscatal.5b02495","title":"Iron-Catalyzed Amination of Sulfides and Sulfoxides with Azides in Photochemical Continuous Flow Synthesis","year":2016,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Université de Montréal; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Amination; Chemistry; Catalysis; Azide; Continuous flow; Stereospecificity; Sulfoxide; Photochemistry; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002621663,0.0004530844,0.0002727131,0.0002474942,0.0001661961,0.0001780601,0.0002971482,0.0002816125,0.0005833586],"category_scores_gemma":[0.0001207158,0.0001763825,0.0002175067,0.0001973067,0.00030619,0.0002433945,0.000214428,0.0003441643,0.0002530318],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000364803,"about_ca_system_score_gemma":0.0002738715,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005870924,"about_ca_topic_score_gemma":0.00126586,"domain_scores_codex":[0.9999062,0.00001335503,0.000007820508,0.00001882144,0.00003073207,0.00002304282],"domain_scores_gemma":[0.999943,0.00001013557,0.00001575899,0.000006596936,0.00001215015,0.00001238101],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006573828,0.00002546344,0.00009964083,0.00005279137,0.000006456057,0.0001012578,0.00002692475,0.0002226233,0.9961957,0.0002781462,0.00005342089,0.00287186],"study_design_scores_gemma":[0.00002226396,0.0002300807,0.0004023882,0.000002925807,0.0000106216,0.000121606,0.000009246237,0.0009107451,0.9970105,0.00006348428,0.001211345,0.000004911525],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9799026,0.001153963,0.01498169,0.00008223873,0.00004891582,0.00007373829,0.000168768,0.0001228338,0.003465232],"genre_scores_gemma":[0.9879721,0.0008073399,0.009245214,0.00001705628,0.00001481821,0.00002555204,0.0001358927,0.000019587,0.001762501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005870924,"threshold_uncertainty_score":0.002646923,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006072937397481445,"score_gpt":0.200155421305924,"score_spread":0.1940824839084425,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}