{"id":"W2233947154","doi":"10.1021/jacs.5b10179","title":"Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic CO<sub>2</sub> Reduction","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced Photocatalysis Techniques","field":"Energy","cited_by":276,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Connaught Fund; Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Ontario Ministry of Economic Development and Innovation","keywords":"Chemistry; Photocatalysis; Frustrated Lewis pair; Reduction (mathematics); Lewis acids and bases; Photochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000349346,0.000285546,0.0005776518,0.00002814822,0.0001231791,0.00002700522,0.0006225889,0.0001263924,0.00001866636],"category_scores_gemma":[0.000191047,0.0001701596,0.001103774,0.0005329862,0.0006910153,0.0001869424,0.00007804693,0.0003289626,0.0000065616],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005680253,"about_ca_system_score_gemma":0.00009772078,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007469032,"about_ca_topic_score_gemma":0.000002751097,"domain_scores_codex":[0.9980695,0.00007816974,0.0006904603,0.0003072362,0.0004234825,0.0004311675],"domain_scores_gemma":[0.9973978,0.0002746461,0.001351642,0.0004901842,0.0003155084,0.0001701672],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002327533,0.0001142752,0.00006328041,0.00001229024,0.0002760486,0.000001652693,0.00009551049,0.0002871385,0.9882616,0.000005588644,0.007154192,0.003495717],"study_design_scores_gemma":[0.0006447075,0.0001673981,0.00003361318,0.00007045935,0.000126848,0.000169924,0.0001217209,0.0002113344,0.9941002,0.001170601,0.002934274,0.0002489745],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960278,0.00004147835,0.002729656,0.0005481887,0.0001051668,0.0003768506,0.00003078203,0.0001017709,0.00003827544],"genre_scores_gemma":[0.9949775,0.0001736497,0.004146634,0.000326335,0.0002283772,0.00001693983,0.000007319584,0.00006642652,0.00005686542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005838593,"threshold_uncertainty_score":0.6938909,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01379278615875093,"score_gpt":0.2679655390145707,"score_spread":0.2541727528558197,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}