{"id":"W2235956054","doi":"10.1039/c5sc03958d","title":"Structural and spectroscopic studies of a rare non-oxido V(<scp>v</scp>) complex crystallized from aqueous solution","year":2016,"lang":"en","type":"article","venue":"Chemical Science","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Lawrence Berkeley National Laboratory; Chemical Sciences, Geosciences, and Biosciences Division; Pacific Northwest National Laboratory; Basic Energy Sciences; Office of Nuclear Energy; Canadian Foundation for Dietetic Research; Office of Science; Nuclear Energy University Program; University of California; U.S. Department of Energy","keywords":"Aqueous solution; Chemistry; Stereochemistry; Crystallography; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001039408,0.0001645095,0.0002562013,0.00001976063,0.0001778196,0.00003843224,0.0003406476,0.00006696876,0.0001363819],"category_scores_gemma":[0.0006418661,0.0001129803,0.00003862382,0.0001704586,0.001508904,0.000263009,0.0001837861,0.000100662,0.000002126991],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001492547,"about_ca_system_score_gemma":0.00007105563,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001150043,"about_ca_topic_score_gemma":7.616148e-7,"domain_scores_codex":[0.9986038,0.000005641986,0.0002364961,0.0004597786,0.0003367903,0.000357506],"domain_scores_gemma":[0.9990494,0.0003353555,0.0001614303,0.000208847,0.0001139552,0.0001310727],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001158492,0.00001130202,0.003026649,0.00009174919,0.00001802829,0.000001929888,0.0003019632,1.359607e-7,0.9943346,0.00001425062,0.000107358,0.002080436],"study_design_scores_gemma":[0.0006157829,0.000009442468,0.001138613,0.0001679911,0.00001647215,0.000006212012,0.0003179358,0.0001912248,0.9953185,0.001969392,0.0001694007,0.00007898954],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958363,0.0006646303,0.0001603668,0.00009662544,0.00003505702,0.00003753236,0.00003007783,0.00003507048,0.003104371],"genre_scores_gemma":[0.9981878,0.00005287952,0.00140651,0.00001965423,0.000125591,0.000005474584,0.000006802843,0.000006729767,0.0001885811],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00291579,"threshold_uncertainty_score":0.5559618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03220686154002858,"score_gpt":0.2953856668246784,"score_spread":0.2631788052846498,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}