{"id":"W2236660347","doi":"10.1039/c5ce02126j","title":"Persistence of C–H⋯π(chelate ring) interactions in the crystal structures of Pd(S<sub>2</sub>COR)<sub>2</sub>. The utility of Pd(S<sub>2</sub>COR)<sub>2</sub>as precursors for palladium sulphide materials","year":2016,"lang":"en","type":"article","venue":"CrystEngComm","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; Workers Compensation Board of Alberta; National Institute for Nanotechnology","funders":"Ministry of Education, India; Ministry of Earth Sciences; Ministry of Higher Education, Malaysia; Alberta Innovates - Technology Futures","keywords":"Ring (chemistry); Chelation; Persistence (discontinuity); Palladium; Chemistry; Crystallography; Crystal (programming language); Crystal structure; Stereochemistry; Inorganic chemistry; Computer science; Catalysis; Organic chemistry; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007667591,0.0001873015,0.0001794174,0.0001244822,0.0002319541,0.0003907253,0.0002883048,0.0002176465,0.003311683],"category_scores_gemma":[0.0003024594,0.0002107277,0.00009158216,0.0002219992,0.0003502978,0.0002661983,0.0002706262,0.0004971708,0.0003275631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004100296,"about_ca_system_score_gemma":0.000446433,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00199245,"about_ca_topic_score_gemma":0.004185254,"domain_scores_codex":[0.9999131,0.00001110652,0.000005034141,0.00002324848,0.00003283477,0.00001478599],"domain_scores_gemma":[0.9998736,0.00002472398,0.00004938614,0.00001809645,0.00001558305,0.00001853848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001632689,0.0001245275,0.005696134,0.0007832629,0.00006561181,0.001361254,0.0006378531,0.006778889,0.9235024,0.00969704,0.009735912,0.03998449],"study_design_scores_gemma":[0.0004671675,0.001273561,0.04379264,0.00005403603,0.0001053432,0.002002543,0.001229797,0.02357224,0.88521,0.004723537,0.03743423,0.0001350066],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9858164,0.0006883774,0.001628857,0.0002722694,0.00004898641,0.00001375954,0.0004069988,0.0001730208,0.01095136],"genre_scores_gemma":[0.996567,0.0002589363,0.00099337,0.0001046862,0.000007440803,0.00001218061,0.0005460994,0.00002138708,0.001488915],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003311683,"threshold_uncertainty_score":0.01107872,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0219891310108206,"score_gpt":0.2553435993239384,"score_spread":0.2333544683131178,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}