{"id":"W2238096199","doi":"10.1002/ejoc.201501592","title":"Enantioselective Total Synthesis of the Proposed Structure of the Endophytic Fungal Metabolite Phomolide G: Structural Revision and Unambiguous Stereochemical Assignment","year":2016,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Diastereomer; Total synthesis; Enantioselective synthesis; Aldol reaction; Stereochemistry; Natural product; Nitrile; Ketone; Alkylation; Aldehyde; Absolute configuration; Substrate (aquarium); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001471723,0.0004090228,0.0002724721,0.00022186,0.0001632968,0.000295176,0.0003044986,0.0002363385,0.001076235],"category_scores_gemma":[0.0001472118,0.0001190414,0.0002238774,0.0002262701,0.0001868353,0.0002340811,0.0003581718,0.000483186,0.0007466851],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002025089,"about_ca_system_score_gemma":0.0004453774,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003967584,"about_ca_topic_score_gemma":0.0005718907,"domain_scores_codex":[0.9999214,0.00001431945,0.000006576203,0.00001719117,0.0000152091,0.00002526953],"domain_scores_gemma":[0.9999349,0.000006968228,0.00001168635,0.00001653377,0.00001256015,0.00001735404],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001204974,0.00002354572,0.0001944617,0.00008651787,0.00001313528,0.0004778264,0.00005260571,0.0004330124,0.9866434,0.0009965614,0.0001125169,0.01084593],"study_design_scores_gemma":[0.00005146239,0.0005478354,0.001345027,0.00001720404,0.00004867735,0.0007759759,0.00004786193,0.000779867,0.9851062,0.0004108789,0.01085077,0.00001820873],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9221072,0.001844891,0.06190861,0.0002694466,0.0001009487,0.0003740432,0.002162237,0.0002452937,0.01098744],"genre_scores_gemma":[0.9603746,0.001877033,0.03343834,0.0001226968,0.00001902514,0.0000937995,0.001098555,0.0000449047,0.00293103],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001076235,"threshold_uncertainty_score":0.003600299,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005588912741140695,"score_gpt":0.2054846267274621,"score_spread":0.1998957139863214,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}