{"id":"W2249791208","doi":"10.1002/chem.201503528","title":"Metal‐Free Dehydrogenation of Amine‐Boranes by Tunable N‐Heterocyclic Iminoboranes","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dehydrogenation; Boranes; Amine gas treating; Chemistry; Metal; Organic chemistry; Catalysis; Boron","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001297523,0.0003835862,0.0002221709,0.000138389,0.0001379936,0.0002251199,0.0003304724,0.0002055697,0.001587075],"category_scores_gemma":[0.0001128784,0.0001936654,0.0001208632,0.00008710937,0.0002200507,0.0003205314,0.0002876826,0.0003463335,0.0004720989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002676292,"about_ca_system_score_gemma":0.0001390361,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003808592,"about_ca_topic_score_gemma":0.001185924,"domain_scores_codex":[0.9998944,0.00001704823,0.000007856269,0.00002201018,0.00002413452,0.0000345571],"domain_scores_gemma":[0.9999495,0.000007333356,0.00001637293,0.000008314157,0.000005036706,0.00001354884],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001238221,0.0000210146,0.00007665037,0.0001494678,0.00001125027,0.00005042786,0.00006411124,0.0002712893,0.9963744,0.0005215328,0.0000852387,0.002250757],"study_design_scores_gemma":[0.00001433265,0.00008594573,0.0002056035,0.000004077445,0.000005333914,0.00003630671,0.00001012287,0.0002725417,0.9971545,0.00002567629,0.002180399,0.000005051185],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9850357,0.00186423,0.003905539,0.00009093909,0.00004373504,0.00003494011,0.0001569393,0.0001848198,0.008683222],"genre_scores_gemma":[0.9959913,0.0004297443,0.001575709,0.00002420418,0.0000048749,0.000008832138,0.00007487225,0.00003044118,0.001860025],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001587075,"threshold_uncertainty_score":0.005309284,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009426742766759618,"score_gpt":0.1995576771379541,"score_spread":0.1901309343711945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}