{"id":"W2254594679","doi":"10.1055/s-0035-1560707","title":"An Azide-Functionalized Nitronyl Nitroxide Radical: Synthesis, Characterization and Staudinger–Bertozzi Ligation Reactivity","year":2015,"lang":"en","type":"article","venue":"Synlett","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Nitroxide mediated radical polymerization; Chemistry; Reactivity (psychology); Azide; Click chemistry; Covalent bond; Polymer chemistry; Staudinger reaction; Combinatorial chemistry; Photochemistry; Organic chemistry; Radical polymerization; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003761416,0.0003269625,0.0002215847,0.0002520783,0.0001664616,0.0001580772,0.0003358461,0.0005772895,0.0007075989],"category_scores_gemma":[0.0002923844,0.0001471235,0.0001251751,0.0001636433,0.0002506922,0.0002491615,0.0001584584,0.0005107995,0.0002543365],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003195019,"about_ca_system_score_gemma":0.0001759104,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005186331,"about_ca_topic_score_gemma":0.0008673787,"domain_scores_codex":[0.9998701,0.00001662776,0.000008357966,0.00003387079,0.0000436146,0.00002749671],"domain_scores_gemma":[0.9998536,0.00003515815,0.00003604013,0.00001983827,0.00003256622,0.00002288516],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002766481,0.00001186822,0.00005280639,0.00002769924,0.000002166679,0.00003011036,0.00002609451,0.00007377064,0.998914,0.000159421,0.00001461342,0.0006598555],"study_design_scores_gemma":[0.000005603566,0.0001578656,0.000394872,0.00000246392,0.000004571199,0.00006516714,0.000006694966,0.0003465049,0.9977628,0.00003790082,0.001209699,0.000005869592],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906164,0.0008971544,0.006797017,0.00006321276,0.00001732223,0.00006551015,0.0001282498,0.00003419816,0.001380855],"genre_scores_gemma":[0.9837387,0.0009862649,0.01182666,0.0000433887,0.00001101531,0.00006942771,0.000364214,0.00001811225,0.00294225],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007075989,"threshold_uncertainty_score":0.002367139,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0142726934683016,"score_gpt":0.2602968129973229,"score_spread":0.2460241195290213,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}