{"id":"W2255259750","doi":"10.1021/om300154m","title":"Pd(η<sup>3</sup>-1-PhC<sub>3</sub>H<sub>4</sub>)(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>), an Unusually Effective Catalyst Precursor for Suzuki–Miyaura Cross-Coupling Reactions Catalyzed by Bis-Phosphine Palladium(0) Compounds","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Phenylboronic acid; Steric effects; Palladium; Medicinal chemistry; Anhydrous; Stereochemistry; Coupling reaction; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003953177,0.0003506857,0.0001936697,0.0002233908,0.0001221831,0.0004652486,0.000399933,0.0003122092,0.001584842],"category_scores_gemma":[0.00029071,0.0002043775,0.0001541157,0.0001907169,0.0002357635,0.0003456672,0.0003279846,0.0003772968,0.0008510355],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000328645,"about_ca_system_score_gemma":0.000118053,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000323945,"about_ca_topic_score_gemma":0.0005920835,"domain_scores_codex":[0.9997802,0.00005135807,0.000015244,0.00004501516,0.00005696999,0.00005116438],"domain_scores_gemma":[0.9998831,0.00003204537,0.00003358813,0.00001435862,0.00001484384,0.00002200754],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001926076,0.00001586584,0.0002761253,0.0001637807,0.00001344769,0.00005282528,0.00004163854,0.0002704617,0.9935243,0.0003490754,0.00008103341,0.00501878],"study_design_scores_gemma":[0.000004322422,0.0001325101,0.0006269676,0.000003687951,0.000009855032,0.00006548563,0.00001288709,0.000322338,0.9973205,0.00002353183,0.001475277,0.000002614598],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9645564,0.006096747,0.01615452,0.00006772819,0.0000313358,0.00006246939,0.0002701184,0.0003037316,0.01245697],"genre_scores_gemma":[0.9922024,0.001382704,0.004068182,0.00002535876,0.000006178059,0.00001648741,0.0002094743,0.00002905126,0.002060084],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001584842,"threshold_uncertainty_score":0.005301774,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01318793827652168,"score_gpt":0.2646522042181237,"score_spread":0.2514642659416021,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}