{"id":"W2255259750","doi":"10.1021/om300154m","title":"Pd(η<sup>3</sup>-1-PhC<sub>3</sub>H<sub>4</sub>)(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>), an Unusually Effective Catalyst Precursor for Suzuki–Miyaura Cross-Coupling Reactions Catalyzed by Bis-Phosphine Palladium(0) Compounds","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Phenylboronic acid; Steric effects; Palladium; Medicinal chemistry; Anhydrous; Stereochemistry; Coupling reaction; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.003507974,0.004645796,0.004419215,0.001759377,0.004048071,0.002731662,0.003388325,0.003228232,0.0002007307],"category_scores_gemma":[0.003271028,0.005325639,0.002694682,0.005193623,0.002572565,0.005114176,0.001491678,0.004506292,0.001724005],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.004994684,"about_ca_system_score_gemma":0.001875498,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004887468,"about_ca_topic_score_gemma":0.0006008954,"domain_scores_codex":[0.9798757,0.0000851564,0.005024057,0.005477936,0.003229676,0.006307511],"domain_scores_gemma":[0.9807746,0.00370765,0.003052517,0.006195826,0.002628813,0.003640557],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001131321,0.004369556,0.004320259,0.001603287,0.002882951,0.00008763224,0.003501804,0.007016033,0.966698,0.0002123973,0.003009632,0.005167147],"study_design_scores_gemma":[0.007533364,0.0004463106,0.003213868,0.0005628247,0.002927147,0.0007790889,0.001559941,0.012866,0.957271,0.0002416898,0.0071811,0.005417701],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9797888,0.001800541,0.001475595,0.000380834,0.0017203,0.004476897,0.00726915,0.002752586,0.0003352613],"genre_scores_gemma":[0.9697384,0.001066666,0.0002470228,0.0003494463,0.003555858,0.002551732,0.02019978,0.002037452,0.0002536358],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01293063,"threshold_uncertainty_score":0.9990532,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01318793827652168,"score_gpt":0.2646522042181237,"score_spread":0.2514642659416021,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}