{"id":"W2256943689","doi":"10.1139/cjc-2015-0547","title":"Oxygen-17 NMR spectroscopy of water molecules in solid hydrates","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Agriculture and Agri-Food Canada; University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chemical shift; Analytical Chemistry (journal); Nuclear magnetic resonance spectroscopy; Solid-state nuclear magnetic resonance; Molecule; Nuclear magnetic resonance; Physical chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006605272,0.0001130352,0.0002025474,0.00004662743,0.00003015354,0.00001048867,0.0002967493,0.0001036775,0.002143226],"category_scores_gemma":[0.00003785358,0.00007703525,0.00008251273,0.00005547572,0.0001140061,0.00007004892,0.0000122944,0.0001602497,0.000003846168],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001632631,"about_ca_system_score_gemma":0.0002741031,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001665682,"about_ca_topic_score_gemma":0.0003367976,"domain_scores_codex":[0.9991318,0.000002941711,0.0003792505,0.0001127514,0.00009070653,0.000282561],"domain_scores_gemma":[0.9992144,0.00002021601,0.0001665841,0.0002177599,0.00009937347,0.0002816714],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007330613,0.00001159763,0.0007983046,0.00003458982,0.00001069857,0.00004069841,0.00005484404,0.00003109894,0.9976244,0.00001865786,0.0009409225,0.0004268509],"study_design_scores_gemma":[0.0002464331,0.000007427087,0.00005955471,0.0001526953,0.000005060288,0.00006448992,0.0000632622,0.000005917392,0.9832096,0.002546361,0.0135331,0.0001061058],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9820064,0.0002742018,0.0006906129,0.0008790197,0.00000660384,0.00002095681,0.00004580364,0.000008329743,0.01606807],"genre_scores_gemma":[0.9972295,0.00005821114,0.001341333,0.00003594972,0.0001128149,0.000004272543,0.000004031946,0.00001743942,0.001196424],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01522313,"threshold_uncertainty_score":0.9987689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006930808726056369,"score_gpt":0.2427924548394696,"score_spread":0.2358616461134132,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}