{"id":"W2257535693","doi":"10.1021/acs.inorgchem.5b02723","title":"Condensation Reactions of Chlorophosphanes with Chalcogenides","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"European Research Council","keywords":"Chemistry; Steric effects; Condensation; Condensation reaction; Transition metal; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Computational chemistry; Organic chemistry; Catalysis; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001009673,0.0001850603,0.0002115381,0.00002122328,0.00005520104,0.000009540589,0.0002328955,0.0001807487,0.005517652],"category_scores_gemma":[0.0002699317,0.0001316063,0.00006563451,0.0001204548,0.0001800187,0.00009250467,0.00003735362,0.0001178778,0.00002799191],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001258097,"about_ca_system_score_gemma":0.0001082852,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003284107,"about_ca_topic_score_gemma":0.000004198124,"domain_scores_codex":[0.9989381,0.000007500336,0.0003086912,0.0002979198,0.0002446261,0.0002031183],"domain_scores_gemma":[0.9986899,0.0002653773,0.0002440056,0.0005787422,0.000147599,0.00007431109],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004735138,0.00006402758,0.003141928,0.0001713534,0.00004909136,0.00000640993,0.00003993008,1.180377e-7,0.9949737,0.00002923884,0.0001008034,0.001376036],"study_design_scores_gemma":[0.0003733908,0.00001069184,0.0002129612,0.0002600983,0.00003586572,0.00006670482,0.0001341693,9.818663e-7,0.9970026,0.0001897956,0.001515549,0.0001971663],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870187,0.0001092193,0.0001440083,0.0001719712,0.00001460665,0.00003873866,0.00003491081,0.0003003021,0.01216751],"genre_scores_gemma":[0.9966437,0.00005428713,0.0003319224,0.00001287947,0.0001068662,0.00002948193,0.000009633152,0.00004383033,0.00276738],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009624986,"threshold_uncertainty_score":0.9953914,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009120483221945672,"score_gpt":0.2080752657742219,"score_spread":0.1989547825522762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}