{"id":"W2257535693","doi":"10.1021/acs.inorgchem.5b02723","title":"Condensation Reactions of Chlorophosphanes with Chalcogenides","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"European Research Council","keywords":"Chemistry; Steric effects; Condensation; Condensation reaction; Transition metal; Medicinal chemistry; Stereochemistry; Combinatorial chemistry; Computational chemistry; Organic chemistry; Catalysis; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000148644,0.0004320885,0.0002025966,0.0002495057,0.0001937984,0.0001965063,0.0002485029,0.0002229348,0.001953486],"category_scores_gemma":[0.000184468,0.0001551588,0.0001503118,0.0002443502,0.0002592675,0.000292286,0.0005121342,0.0003359825,0.0005457019],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004319886,"about_ca_system_score_gemma":0.0003581431,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000342975,"about_ca_topic_score_gemma":0.0009802361,"domain_scores_codex":[0.9998358,0.00003349988,0.00001030172,0.00003289815,0.00004197726,0.00004555189],"domain_scores_gemma":[0.9999425,0.00001443381,0.00001288822,0.000008203394,0.000008659678,0.00001319904],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001372196,0.00001149174,0.0001684333,0.0002056085,0.00001371902,0.0002068748,0.0001194068,0.0004443375,0.9916862,0.001586673,0.000174221,0.005245714],"study_design_scores_gemma":[0.000009075467,0.00009267116,0.0002558826,0.000004409182,0.000004957613,0.000125953,0.00001672917,0.0002040669,0.9963086,0.00007840493,0.002894323,0.000004893644],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9719613,0.001913288,0.009723223,0.0001401074,0.00004429621,0.00009351698,0.0003889429,0.0001906589,0.01554473],"genre_scores_gemma":[0.9926731,0.001131695,0.003021111,0.00003577513,0.000009872759,0.00003960036,0.0002332734,0.00003919821,0.002816442],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001953486,"threshold_uncertainty_score":0.006535053,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009120483221945672,"score_gpt":0.2080752657742219,"score_spread":0.1989547825522762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}