{"id":"W2259435605","doi":"10.1021/ja5006724","title":"Reactivity of Ruthenium Phosphido Species Generated through the Deprotonation of a Tripodal Phosphine Ligand and Implications for Hydrophosphination","year":2014,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Phosphine; Ligand (biochemistry); Deprotonation; Ruthenium; Moiety; Medicinal chemistry; Stereochemistry; Reactivity (psychology); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001443907,0.0002369439,0.0001693676,0.0001217664,0.0001025783,0.0002795271,0.000320916,0.0003630792,0.001107264],"category_scores_gemma":[0.0001832867,0.0001435726,0.0001446971,0.00008548301,0.0002280546,0.0002408582,0.000216248,0.0004058971,0.0002715414],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003023608,"about_ca_system_score_gemma":0.00008719298,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003192977,"about_ca_topic_score_gemma":0.0003118041,"domain_scores_codex":[0.9998989,0.0000202218,0.000004747046,0.00002067004,0.00002269246,0.00003274016],"domain_scores_gemma":[0.9999484,0.00001304725,0.00001630842,0.000005994742,0.000007186696,0.000009097337],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000138543,0.00001635891,0.0001437247,0.00006813536,0.000008966535,0.0001454285,0.00004934939,0.000668169,0.9970071,0.000452325,0.0000609286,0.001241054],"study_design_scores_gemma":[0.00001882132,0.0002225459,0.0005805411,0.000005302877,0.000007240705,0.000145672,0.00002646747,0.002145587,0.9960925,0.0000747833,0.000672094,0.000008365166],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973712,0.0003266881,0.0007558936,0.00003932807,0.000004332204,0.000008198045,0.00006041255,0.00003450848,0.001399413],"genre_scores_gemma":[0.999035,0.0001491536,0.0003694376,0.00001235298,0.000001774289,0.000005891914,0.000051421,0.000006727494,0.0003682958],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001107264,"threshold_uncertainty_score":0.00370419,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01167469157986613,"score_gpt":0.2521757934291947,"score_spread":0.2405011018493285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}