{"id":"W2263133727","doi":"10.1021/jacs.5b13273","title":"Tracking Sodium-Antimonide Phase Transformations in Sodium-Ion Anodes: Insights from Operando Pair Distribution Function Analysis and Solid-State NMR Spectroscopy","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advancements in Battery Materials","field":"Engineering","cited_by":206,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Argonne National Laboratory; Gonville and Caius College, University of Cambridge; Office of Science; Agence Nationale de la Recherche; European Research Council; University of Cambridge; Engineering and Physical Sciences Research Council; U.S. Department of Energy","keywords":"Chemistry; Sodium; Ion; Solid-state nuclear magnetic resonance; Antimonide; Nuclear magnetic resonance spectroscopy; Phase (matter); Analytical Chemistry (journal); Spectroscopy; Anode; Solid-state; Inorganic chemistry; Chemical physics; Physical chemistry; Nuclear magnetic resonance; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001670277,0.0001612139,0.0004320926,0.00004083825,0.00007165344,0.00004825803,0.0001617214,0.00004157476,0.00002293887],"category_scores_gemma":[0.00003057212,0.00009822941,0.0002269837,0.0004117484,0.0001582453,0.0004635272,0.0000249406,0.0001874142,0.00000145338],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003150898,"about_ca_system_score_gemma":0.00001569482,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002478992,"about_ca_topic_score_gemma":0.00000542681,"domain_scores_codex":[0.9988188,0.00005855425,0.0005708335,0.0001254718,0.0002207362,0.0002056175],"domain_scores_gemma":[0.99935,0.0001120204,0.0002799149,0.0001428044,0.00005060572,0.00006466148],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001149805,0.00005587774,0.003359033,0.000009164606,0.0003145161,8.37444e-7,0.0004315533,0.001060916,0.991511,0.000001291079,0.0002724981,0.002868292],"study_design_scores_gemma":[0.001820996,0.000052716,0.009282872,0.0000727889,0.0002985892,0.000003619994,0.000208242,0.002018545,0.985314,0.0005615182,0.00020836,0.0001577734],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8318373,0.00008227694,0.1673607,0.0004176151,0.0001174391,0.00007545045,0.00008095337,0.000024407,0.000003844331],"genre_scores_gemma":[0.9976091,0.0004144683,0.001682928,0.0001321016,0.0001233677,0.000004527943,0.00001556814,0.00001539356,0.000002517754],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1657719,"threshold_uncertainty_score":0.4005679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007925273961151086,"score_gpt":0.257538912751305,"score_spread":0.2496136387901539,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}