{"id":"W2263253015","doi":"10.1021/ic000970n","title":"Syntheses, Structures, and Stabilities of [PPh<sub>4</sub>][WS<sub>3</sub>(SR)] (R = <sup>i</sup>Bu, <sup>i</sup>Pr, <sup>t</sup>Bu, Benzyl, Allyl) and [PPh<sub>4</sub>][MoS<sub>3</sub>(S<sup>t</sup>Bu)]","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Calgary","funders":"","keywords":"Monoclinic crystal system; Triclinic crystal system; Chemistry; Alkyl; Crystal structure; Crystallography; Halide; Stereochemistry; Acetonitrile; Medicinal chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006986871,0.0002398798,0.0001582123,0.000138946,0.0001729358,0.0001770043,0.0001667912,0.0001445745,0.001831242],"category_scores_gemma":[0.0001699341,0.0001531587,0.0001625054,0.0002331765,0.0001540456,0.0001879873,0.0001353697,0.0002894836,0.0003623079],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002166754,"about_ca_system_score_gemma":0.0002990584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007666806,"about_ca_topic_score_gemma":0.002097402,"domain_scores_codex":[0.9999534,0.000006219212,0.000004334515,0.000008064808,0.00001915859,0.000008810332],"domain_scores_gemma":[0.9999357,0.000009390771,0.00002206258,0.000008463272,0.00001328008,0.00001112814],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006071611,0.00001040181,0.0001281882,0.00007236857,0.000009676123,0.00004321522,0.00003419639,0.0003177316,0.9960791,0.0002486572,0.00007549334,0.002920323],"study_design_scores_gemma":[0.000008761588,0.0001300735,0.0009526028,0.000002645746,0.00001817215,0.00009758987,0.00001579679,0.0003366435,0.9957715,0.00006998512,0.002588653,0.000007686484],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9861156,0.001557015,0.005876205,0.00006864684,0.00002598049,0.00007332298,0.0006510001,0.0001575543,0.005474726],"genre_scores_gemma":[0.9874777,0.001473634,0.005465023,0.00004189976,0.00001250848,0.00005862356,0.0007851817,0.00007247367,0.004613025],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001831242,"threshold_uncertainty_score":0.006126106,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0106992533563168,"score_gpt":0.2024594356969728,"score_spread":0.1917601823406559,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}