{"id":"W2263701154","doi":"10.1021/acs.jced.5b01061","title":"The Volumetric Properties of Carbonyl Sulfide and Carbon Dioxide Mixtures from <i>T</i> = 322 to 393 K and <i>p</i> = 2.5 to 35 MPa: Application to COS Hydrolysis in Subsurface Injectate Streams","year":2016,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Gibbs free energy; Chemistry; Carbon dioxide; Thermodynamics; Mixing (physics); Carbonyl sulfide; Hydrolysis; Enthalpy; High pressure; Equation of state; Sulfide; Analytical Chemistry (journal); Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001916552,0.0002882929,0.0001886952,0.0003451407,0.0002040359,0.000338546,0.0003065223,0.0002688433,0.001264636],"category_scores_gemma":[0.0004099421,0.0002084351,0.0002018779,0.0003856051,0.0003569888,0.0004051923,0.0002189864,0.0003286391,0.0002177191],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003475145,"about_ca_system_score_gemma":0.0001896277,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002565722,"about_ca_topic_score_gemma":0.002089975,"domain_scores_codex":[0.9998956,0.000008537511,0.000005644882,0.00002121972,0.00005276616,0.00001631229],"domain_scores_gemma":[0.9999058,0.00002980278,0.00001897298,0.000004463965,0.0000312441,0.000009733418],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002132434,0.00002267222,0.00543227,0.00005829795,0.000009428817,0.0000925884,0.0001647089,0.002042513,0.9879946,0.0001526117,0.00005694015,0.003759968],"study_design_scores_gemma":[0.000006352529,0.0001410637,0.01349413,0.00000427611,0.000009708164,0.00006227702,0.00009948736,0.01036543,0.9753885,0.00004970051,0.0003668023,0.00001240164],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975669,0.00008728865,0.001131932,0.00001799529,0.000002750131,0.000008461617,0.0002959667,0.00004285909,0.000845902],"genre_scores_gemma":[0.9989048,0.00007211546,0.0005615103,0.000003489051,0.000001424699,0.000006794404,0.0002004851,0.00001337878,0.0002360445],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002565722,"threshold_uncertainty_score":0.005101621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006727292284818716,"score_gpt":0.192075934078302,"score_spread":0.1853486417934833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}