{"id":"W2263881191","doi":"10.1002/chem.201504683","title":"Synthesis and Aggregation Behavior of Chiral Naphthoquinoline Petroporphyrin Asphaltene Model Compounds","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Institute for Oil Sands Innovation, University of Alberta; Natural Sciences and Engineering Research Council of Canada","keywords":"Porphyrin; Chemistry; Supramolecular chemistry; Circular dichroism; Steric effects; Asphaltene; Pyridine; Stereochemistry; Molecule; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007965463,0.0001776049,0.0001209513,0.0001388069,0.0001030813,0.0001332765,0.0001310468,0.0001285372,0.0005272178],"category_scores_gemma":[0.0001240646,0.00006755088,0.00006407216,0.0001407538,0.00009557856,0.00009971956,0.00008950812,0.0001706453,0.0001552529],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000293506,"about_ca_system_score_gemma":0.0001218866,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006536931,"about_ca_topic_score_gemma":0.0008963161,"domain_scores_codex":[0.9999563,0.000008979149,0.000003080489,0.00001020178,0.00001489713,0.000006522777],"domain_scores_gemma":[0.9999354,0.00001099966,0.00001809872,0.000007848711,0.000008601893,0.0000190952],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003913661,0.00002426616,0.00008700311,0.00002283541,0.000003022604,0.00004386869,0.00001436169,0.0007822879,0.9977478,0.0001910303,0.00001862381,0.001025753],"study_design_scores_gemma":[0.00001387188,0.0003270804,0.0007462209,0.000002917298,0.00000634256,0.00005659924,0.00001057786,0.002535933,0.9950545,0.00003528149,0.00120658,0.000004070115],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970883,0.0002743315,0.001436734,0.00001762461,0.000004341537,0.00002342375,0.0001327929,0.00002274043,0.0009995878],"genre_scores_gemma":[0.9972956,0.0002650175,0.001610548,0.000006393189,0.000001556158,0.000013765,0.0001125352,0.000005611416,0.0006890693],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006536931,"threshold_uncertainty_score":0.002129555,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01637086144074392,"score_gpt":0.2301704837241972,"score_spread":0.2137996222834533,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}