{"id":"W2266039312","doi":"10.1080/15421406.2015.1096450","title":"Nanocrystallization of Insoluble Copper(I) Complex and Formation Mechanism","year":2015,"lang":"en","type":"article","venue":"Molecular Crystals and Liquid Crystals","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Hosokawa Powder Technology Foundation; University of Saskatchewan","keywords":"Acetonitrile; Nanocrystal; Copper; Halide; Ligand (biochemistry); Chemistry; Chemical engineering; Reaction mechanism; Materials science; Inorganic chemistry; Nanotechnology; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000106467,0.0002300367,0.0002711694,0.00009668619,0.0002490859,0.0003370706,0.0003154592,0.0002685637,0.000646608],"category_scores_gemma":[0.0001949287,0.0001528036,0.0001760089,0.00009410587,0.00024392,0.0002975585,0.0002129651,0.0003237786,0.0001581386],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005591611,"about_ca_system_score_gemma":0.0002266955,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00199765,"about_ca_topic_score_gemma":0.002586912,"domain_scores_codex":[0.9998569,0.00001260105,0.00001048778,0.00004793908,0.00003337619,0.00003868255],"domain_scores_gemma":[0.9999361,0.00001153021,0.00001722746,0.000009617146,0.00001558261,0.000009842825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000246379,0.00001093467,0.000128091,0.0000556832,0.00000379118,0.0001163149,0.00003794705,0.0001748157,0.9974101,0.0006077582,0.00009137782,0.001338542],"study_design_scores_gemma":[0.00000462529,0.00001636984,0.000192034,0.000001276844,0.000003244957,0.00005199305,0.000009777873,0.0007434089,0.9982815,0.00003198016,0.0006615608,0.000002310655],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.977373,0.001609882,0.01525924,0.0002410599,0.00003958082,0.00007582784,0.0001649267,0.0001663811,0.005070021],"genre_scores_gemma":[0.9871918,0.000504849,0.009368081,0.00005539882,0.000008325176,0.00002961993,0.000124832,0.00003440054,0.002682622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00199765,"threshold_uncertainty_score":0.00405705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02914464219296325,"score_gpt":0.2489998630150163,"score_spread":0.219855220822053,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}