{"id":"W2267400237","doi":"10.1039/c5dt04481b","title":"Ru alkylidene compounds bearing tridentate, dianionic ligands: Lewis acid activation and olefin metathesis","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Olefin metathesis; Cationic polymerization; Chemistry; Catalysis; Olefin fiber; Metathesis; Lewis acids and bases; Salt metathesis reaction; Medicinal chemistry; Ring-opening metathesis polymerisation; Polymer chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002739944,0.0002606017,0.0003088377,0.00008399363,0.0002626353,0.00007529419,0.0001954539,0.0001836959,0.002425047],"category_scores_gemma":[0.0001258872,0.0002219499,0.0001356832,0.000203097,0.0001244498,0.0003267403,0.00001509317,0.0002104515,0.00003724583],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001940725,"about_ca_system_score_gemma":0.00006722735,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009607246,"about_ca_topic_score_gemma":0.00002195478,"domain_scores_codex":[0.9985086,0.0000334249,0.0003851285,0.000477265,0.0002578757,0.0003377518],"domain_scores_gemma":[0.9986264,0.0005474931,0.0001285174,0.0004675574,0.00005049465,0.0001795637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002912635,0.00007321039,0.0001840696,0.00006104296,0.000110028,0.000002241474,0.0002260133,0.000001732716,0.9518088,0.00001953428,0.00003973474,0.04744452],"study_design_scores_gemma":[0.0009701822,0.00001217718,0.000445712,0.0001388998,0.0001537037,0.00006806657,0.000291981,0.00003062402,0.9940748,0.0003025356,0.003229517,0.0002817955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8542463,0.0003028931,0.1383923,0.002263631,0.000193716,0.0001181975,0.0001313015,0.0003697257,0.003981935],"genre_scores_gemma":[0.9936101,0.0003718951,0.002625608,0.00003868348,0.0001129531,0.00005032745,0.00001232054,0.00005736348,0.003120737],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1393639,"threshold_uncertainty_score":0.9984869,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02058388756000277,"score_gpt":0.2586208062882931,"score_spread":0.2380369187282903,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}